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Polyoxometalate decorated graphene oxide/sulfonated poly(arylene ether ketone) block copolymer composite membrane for proton exchange membrane fuel cell operating under low relative humidity

Title
Polyoxometalate decorated graphene oxide/sulfonated poly(arylene ether ketone) block copolymer composite membrane for proton exchange membrane fuel cell operating under low relative humidity
Author(s)
Oh, KwangjinSon, ByungrakSanetuntikul, JakkidShanmugam, Sangaraju
Issued Date
2017-11
Citation
Journal of Membrane Science, v.541, pp.386 - 392
Type
Article
Author Keywords
Phosphotungstic acidBlock copolymerComposite membraneProton conductivityFuel cell performance
Keywords
POLYMER ELECTROLYTE MEMBRANESSILICA PARTICLESOXIDEPERFORMANCESULFONE)NANOPARTICLESCONDUCTIVITYENHANCEMENTNANOTUBESTITANIA
ISSN
0376-7388
Abstract
A phosphotungstic acid (PW) decorated graphene oxide (GO) is explored as a filler for sulfonated poly(arylene ether ketone) (SPAEK) block copolymer. The SPAEK/PW-mGO composite membrane shows higher proton conductivity than a pristine SPAEK membrane. At 80°C under 25% relative humidity (RH) condition, the fuel cell configured with the SPAEK/PW-mGO composite membrane shows improved fuel cell performance. A maximum power density of 772mWcm−2 is observed for the SPAEK/PW-mGO composite membrane, whereas the pristine SPAEK membrane exhibits a maximum power density of 10mWcm−2 operated under 25% RH at 80°C. Compared with the NRE-212 membrane, the SPAEK/PW-mGO composite membrane exhibits 4.8-times higher maximum power density. Furthermore, the maximum current density of the SPAEK/PW-mGO composite membrane (2271mAcm−2) is much higher than pristine SPAEK (39mAcm−2) and NRE-212 (734mAcm−2) membranes. © 2017 Elsevier B.V.
URI
http://hdl.handle.net/20.500.11750/56366
DOI
10.1016/j.memsci.2017.07.020
Publisher
Elsevier B.V.
Related Researcher
  • 손병락 Son, Byungrak 에너지환경연구부
  • Research Interests 연료전지; Fuel Cell; 하이브리드 전원; Hybrid Power; 스택; Stack; 촉매; Catalyst; 연료전지시스템; Fuel Cell System;센서네트워크;Sensor Network
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Appears in Collections:
Department of Energy Science and Engineering Advanced Energy Materials Laboratory 1. Journal Articles
Division of Energy Technology 1. Journal Articles

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