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Effect of VI/II Gas Ratio on the Epitaxial Growth of ZnO Films by Metalorganic Chemical Vapor Deposition

Title
Effect of VI/II Gas Ratio on the Epitaxial Growth of ZnO Films by Metalorganic Chemical Vapor Deposition
Author(s)
Choi, Yong-SeokHwang, Dae-KueKwon, Bong-JoonKang, Jang-WonCho, Yong-HoonPark, Seong-Ju
Issued Date
2011-10
Citation
Japanese Journal of Applied Physics, v.50, no.10
Type
Article
Keywords
Atomic Force MicroscopyDEVICESemISSIONEpitaxial FilmsEpitaxial GrowthExcitonic emissionExcitonsFilm GrowthFlat TerracesFree-Exciton emissionsGas RatioLIGHT-emITTING-DIODESLongitudinal Optical PhononsLow Temperature PhotoluminescenceMetallic FilmsMetallorganic Chemical Vapor DepositionMOCVDNeutral DonorOptical QualitiesPHOTOLUMINESCENCERoot Mean Square RoughnessTHIN-FILMSZinc OxideZnOZnO Films
ISSN
0021-4922
Abstract
We report the effect of the VI/II ratio on the metalorganic chemical vapor deposition (MOCVD) growth of ZnO film. The surface of ZnO film becomes very smooth as the VI/II ratio increases. Atomic force microscopy measurement shows that ZnO films grown at a VI/II ratio of 25,000 have atomically flat terraces with a root-mean-square roughness of 0.2 nm. Low-temperature photoluminescence spectra also reveal a very sharp excitonic emission comprised of a neutral donor bound exciton emission and a free exciton emission with first and second longitudinal optical (LO) phonon replicas, indicating that the ZnO epilayer is of a high optical quality. © 2011 The Japan Society of Applied Physics.
URI
http://hdl.handle.net/20.500.11750/56410
DOI
10.1143/JJAP.50.105502
Publisher
Institute of Physics Publishing
Related Researcher
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Division of Energy Technology 1. Journal Articles

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