금속 양이온 배위형 D-π-A 발색단을 포함하는 폴리머의 합성 및 박막화와 광학특성

Abstract

Donor-pi-acceptor (D-pi-A) type chromophore-based polymers were newly synthesized. These polymers exhibited absorption peak due to intramolecular charge transfer (ICT) in a visible range as well as absorption peak due to carbonyl group in both solution and film state by measuring UV visible spectra. The addition of Eu(3+) ion into the polymers induced red-shift in absorption due to ICT and the color changes from yellow to red in the solution and film were observed by naked eyes. The contents of crosslinking agent influenced the features and solubility of the polymers. In addition, the contents of crosslinking agent and the Eu(3+) ion addition improved film-forming ability.