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Hydroquinone-treated Cu3(BTC)2: a mixed-valence Cu(i/ii) MOF catalyst for efficient cycloadditions

Title
Hydroquinone-treated Cu3(BTC)2: a mixed-valence Cu(i/ii) MOF catalyst for efficient cycloadditions
Author(s)
Park, Sun HoKim, Hye MiDiaz-Ramirez, Mariana LizethLee, SunggiJeong, Nak Cheon
Issued Date
2024-12
Citation
Chemical Communications, v.60, no.98, pp.14577 - 14580
Type
Article
Keywords
METAL-ORGANIC FRAMEWORKSREDOX ACTIVITYSITESOXIDATIONACID
ISSN
1359-7345
Abstract
We present mixed-valence Cu(I)1Cu(II)2(BTC)2 [henceforth Cu(I/II)-HKUST-1], post-synthetically prepared via the hydroquinone (H2Q) treatment of Cu(II)3(BTC)2 (also referred to as HKUST-1) and its subsequent catalytic activity.This Cu(I/II)-HKUST-1 exhibits exceptional structural integrity and superior catalytic performance in the copper-catalyzed azide-alkyne cycloaddition (CuAAC) reaction between phenylacetylene and benzyl azide.These findings highlight the potential of mixed-valence Cu-based MOFs as effective and sustainable heterogeneous catalysts for organic transformations, paving the way for future advancements in MOF-based catalysis. © The Royal Society of Chemistry 2024.
URI
http://hdl.handle.net/20.500.11750/57219
DOI
10.1039/d4cc04294h
Publisher
Royal Society of Chemistry
Related Researcher
  • 이성기 Lee, Sunggi
  • Research Interests Organic synthesis; Catalyst development; Reaction development; Radical chemistry; Stereoselective reaction
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Appears in Collections:
Department of Physics and Chemistry Supramolecular Inorganic Chemistry Laboratory 1. Journal Articles
Department of Physics and Chemistry Organic Synthesis & Catalysis Lab 1. Journal Articles

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