Title

Synthesis and Electrochemical Characterization of Water-free Prussian Blue analogues as Magnesium Battery Cathode Materials

Alternative Title

마그네슘 배터리 양극 물질로서 무수 프러시안 블루 유사체의 합성과 전기화학적 특성 평가

DGIST Authors

Jiwon Hwang ; Seung-Tae Hong ; Hochun Lee

Advisor

홍승태

Co-Advisor(s)

Hochun Lee

Issued Date

2025

Awarded Date

2025-02-01

Citation

Jiwon Hwang. (2025). Synthesis and Electrochemical Characterization of Water-free Prussian Blue analogues as Magnesium Battery Cathode Materials. doi: 10.22677/THESIS.200000844456

Type

Thesis

Description

Prussian blue analogues, Cathode materials, Multivalent-ion batteries, Magnesium batteries

Table Of Contents

Ⅰ. Introduction
1.1. Why rechargeable magnesium batteries (RMBs)? 1
1.2. Challenges in cathode development for RMBs 2
1.3. Prussian Blue analogues (PBAs) as host materials 3

Ⅱ. Experimental section
2.1. Material synthesis 5
2.2. Material Characterization 6
2.3. Electrochemical Characterization 6
2.4. Galvanostatic intermittent titration technique (GITT) analysis 8
2.5. Structural analysis 8

Ⅲ. Results and Discussion
3.1. Synthesis of iron hexacyanoferrate 9
3.2. Electrochemical characterization 18
3.3. Mg2+ intercalation mechanism 22
3.4. Compatibility of FeHCF with a Mg metal anode 26

IV. Conclusion 28

V. References 29

요약문

URI

http://hdl.handle.net/20.500.11750/58045
http://dgist.dcollection.net/common/orgView/200000844456

DOI

10.22677/THESIS.200000844456

Degree

Master

Department

Department of Energy Science and Engineering

Publisher

DGIST

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