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Strong Coordination at Open-Metal Sites Enhances Hydrolytic Stability of Metal-Organic Frameworks
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dc.contributor.advisor 정낙천 -
dc.contributor.author Jaehyeuk Choi -
dc.date.accessioned 2025-02-28T21:02:51Z -
dc.date.available 2025-02-28T21:02:51Z -
dc.date.issued 2025 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/58069 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000843635 -
dc.description Metal-Organic Frameworks, Open-Metal-Sites, Strong coordination, XRD, NMR -
dc.description.tableofcontents I. INTRODUCTION 1
II. EXPERIMENTAL METHODS & MATERIALS 3
III. RESULTS & DISCUSSION 5
3.1. HK structural features and hypothesis 5
3.1.1. Sample preparation and bonding strength 7
3.1.2. PXRD change and definition of calibrated retention ratio 9
3.1.3. Hydrolytic Stability and Confirmation of Metal-Linker Connectivity 11
3.2. Maintaining crystallinity of MOF due to connectivity of metal and organic ligands 13
3.2.1. Maintaining crystallinity of MOF due to connectivity of metal and organic ligands 15
3.2.2. Structure of HK and the reason for stability up to a coordination ratio of 0.3 16
IV. CONCLUSIONS 18
V. REFERENCES 19
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dc.format.extent 23 -
dc.language eng -
dc.publisher DGIST -
dc.title Strong Coordination at Open-Metal Sites Enhances Hydrolytic Stability of Metal-Organic Frameworks -
dc.title.alternative 열린 금속 자리의 강한 배위결합을 통한 금속유기구조체의 수분안정성 향상 -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000843635 -
dc.description.degree Master -
dc.contributor.department Department of Physics and Chemistry -
dc.identifier.bibliographicCitation Jaehyeuk Choi. (2025). Strong Coordination at Open-Metal Sites Enhances Hydrolytic Stability of Metal-Organic Frameworks. doi: 10.22677/THESIS.200000843635 -
dc.contributor.coadvisor Seong Kyun Kim -
dc.date.awarded 2025-02-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.MM 최73 202502 -
dc.date.accepted 2025-01-20 -
dc.contributor.alternativeDepartment 화학물리학과 -
dc.subject.keyword Metal-Organic Frameworks, Open-Metal-Sites, Strong coordination, XRD, NMR -
dc.contributor.affiliatedAuthor 최재혁 -
dc.contributor.affiliatedAuthor Nak Cheon Jeong -
dc.contributor.affiliatedAuthor Seong Kyun Kim -
dc.contributor.alternativeName 최재혁 -
dc.contributor.alternativeName Nak Cheon Jeong -
dc.contributor.alternativeName 김성균 -
dc.rights.embargoReleaseDate 2030-02-28 -
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