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The Giese reaction of alkyl bromides using amine carboxyboranes
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- Title
- The Giese reaction of alkyl bromides using amine carboxyboranes
- Issued Date
- 2025-03
- Citation
- Park, Changhee. (2025-03). The Giese reaction of alkyl bromides using amine carboxyboranes. Organic Chemistry Frontiers, 12(6), 1874–1878. doi: 10.1039/d4qo02325k
- Type
- Article
- Keywords
- HALOGEN-ATOM TRANSFER ; RADICALS ; HALIDES ; POLARITY-REVERSAL CATALYSIS ; AGENTS
- ISSN
- 2052-4110
- Abstract
-
Amine carboxyborane enabled efficient halogen atom transfer (XAT) with 1 degrees, 2 degrees, and 3 degrees alkyl bromides, resulting in Giese addition products with various electron-deficient double bonds. Moreover, direct addition of several boryl radicals was also possible using several ligated carboxyboranes.
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- Publisher
- Royal Society of Chemistry
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