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MoS₂-Pseudo-Crown Ether-Based Membrane for Highly Selective Li⁺/Na⁺ Ion Separation
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dc.contributor.advisor 박치영 -
dc.contributor.author Yoona Kim -
dc.date.accessioned 2026-01-23T10:55:32Z -
dc.date.available 2026-01-23T10:55:32Z -
dc.date.issued 2026 -
dc.identifier.uri https://scholar.dgist.ac.kr/handle/20.500.11750/59679 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000946620 -
dc.description Direct lithium extraction (DLE), Resource recovery, Ion-selective membrane, Lithium separation, Two-dimensional (2D) nanofluidic, Molybdenum disulfide (MoS₂) membranes, Pseudo-crown ether (PCE), Concentration-gradient-driven separation, Smart ion gating behavior -
dc.description.tableofcontents Ⅰ. Introduction 1
1.1 Research Background 1
1.2 Sustainable Lithium Extraction Technology 2
1.2.1 Direct Lithium Extraction (DLE) 2
1.2.2 Classification of DLE Technologies 3
1.3 Nanofiltration Membrane technologies for lithium extraction 4
1.4 Design of Nanoconfined Channels for Ion Separation 6
1.4.1 Molybdenum Disulfide (MoS₂) 6
1.4.2 Polydopamine (PDA) 6
1.4.3 PCE@MoS₂/PDA Sub-nanochannel 7
Ⅱ. Experimental Method & Materials 9
2.1 Meterials 9
2.2 Synthesis of Monolayer MoS₂ 9
2.3 Polymerization of PCE 10
2.4 Preparation of the PCE@MoS₂/PDA membrane 11
2.5 Characterization 11
2.6 Evaluation of Water and Salt Transport Properties 12
2.6.1 Dead-end cell (pressure-driven) 12
2.6.2 H-cell (concentration gradient-driven) 13
Ⅲ. Results & Discussion 15
3.1 Charecterization of PCE 15
3.2 Characterization of PCE@MoS₂/PDA Nanochannels 18
3.3 Ion Transport and Selectivity Performance of PCE@MoS₂/PDA Membrane 22
3.3.1 Evaluation of Ion Permeability and Rejection 22
3.3.2 Evaluation of Ion Permeability and Selectivity 23
3.4 pH-responsive and Selective Ion Separation Performance Nanochannel 25
3.5 Ion Selective Transport Mechanism in PCE@MoS₂/PDA Nanochannel 27
Ⅳ. Conclusion 29
Ⅴ. Reference 30
Ⅵ. Summary 30
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dc.format.extent 34 -
dc.language eng -
dc.publisher DGIST -
dc.title MoS₂-Pseudo-Crown Ether-Based Membrane for Highly Selective Li⁺/Na⁺ Ion Separation -
dc.title.alternative 이황화몰리브덴 및 슈도-크라운 에터 기반 분리막을 이용한 고선택성 리튬/소듐 이온 분리 -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000946620 -
dc.description.degree Master -
dc.contributor.department Department of Energy Science and Engineering -
dc.contributor.coadvisor Dong Hae Ho -
dc.date.awarded 2026-02-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.EM 김66 202602 -
dc.date.accepted 2026-01-19 -
dc.contributor.alternativeDepartment 에너지공학과 -
dc.subject.keyword Direct lithium extraction (DLE), Resource recovery, Ion-selective membrane, Lithium separation, Two-dimensional (2D) nanofluidic, Molybdenum disulfide (MoS₂) membranes, Pseudo-crown ether (PCE), Concentration-gradient-driven separation, Smart ion gating behavior -
dc.contributor.affiliatedAuthor Yoona Kim -
dc.contributor.affiliatedAuthor Chiyoung Park -
dc.contributor.affiliatedAuthor Dong Hae Ho -
dc.contributor.alternativeName 김윤아 -
dc.contributor.alternativeName Chiyoung Park -
dc.contributor.alternativeName 호동해 -
dc.rights.embargoReleaseDate 2031-02-28 -
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