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  Department of Physics and Chemistry Theses Master

Photocatalytic Activation of N-X Bonds via Amine-Ligated Boranes and its Applications

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dc.contributor.advisor 이성기 -
dc.contributor.author Seongmin Park -
dc.date.accessioned 2026-01-23T10:57:43Z -
dc.date.available 2026-01-23T10:57:43Z -
dc.date.issued 2026 -
dc.identifier.uri https://scholar.dgist.ac.kr/handle/20.500.11750/59741 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000945184 -
dc.description amine-ligated borane, boryl radical, photocatalysis, radical addition -
dc.description.tableofcontents Ⅰ. Introduction 1
1.1 Introduction 1
Ⅱ. Results and Discussion 8
2.1 Cleavage of N-X bond 8
2.1.1 Cleavage of N-O bond 8
2.1.2 Cleavage of N-C bond 8
2.1.3 Cleavage of N-N bond 9
2.2 Radical addition to alkene 10
2.2.1 Intramolecular carbon radical addition to alkenes 10
2.2.2 Intramolecular nitrogen radical addition to alkenes 10
2.2.3 Intramolecular mitrogen radical cyclization 11
2.3 Reaction optimization 11
2.3.1 Photocatalyst screening 11
2.3.2 Disulfide and Thiol screening 12
2.3.3. Solvent screening 14
2.3.4. Radical acceptor screening 15
2.4 Our proposed mechanism 16
2.5 Control experiment 18
2.6 Stability test 19
2.7 One-pot reaction 20
2.8 Amine-ligated carboxyborane synthesis 21
Ⅲ. Conclusion 24
3.1 Conclusion 24
Ⅳ. Experimental Data 26
Ⅵ. References 39
Ⅶ. 국문 요약문 43		 -
dc.format.extent 43 -
dc.language eng -
dc.publisher DGIST -
dc.title Photocatalytic Activation of N-X Bonds via Amine-Ligated Boranes and its Applications -
dc.title.alternative 아민이 배위된 보레인을 활용한 N-X (X = 탄소, 질소, 산소) 결합의 광촉매적 활성화 -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000945184 -
dc.description.degree Master -
dc.contributor.department Department of Physics and Chemistry -
dc.date.awarded 2026-02-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.MM 박54 202602 -
dc.date.accepted 2026-01-19 -
dc.contributor.alternativeDepartment 화학물리학과 -
dc.subject.keyword amine-ligated borane, boryl radical, photocatalysis, radical addition -
dc.contributor.affiliatedAuthor Seongmin Park -
dc.contributor.affiliatedAuthor Sunggi Lee -
dc.contributor.alternativeName 박성민 -
dc.contributor.alternativeName Sunggi Lee -
dc.rights.embargoReleaseDate 2029-02-28 -
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