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  Department of Physics and Chemistry Theses Master

Synthesis of CF₂H-Substituted Alkanes via NiH-Catalyzed Hydroalkylation of Unactivated Alkenes

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dc.contributor.advisor 서상원 -
dc.contributor.author Gyuhwan Sim -
dc.date.accessioned 2026-01-23T10:57:47Z -
dc.date.available 2026-01-23T10:57:47Z -
dc.date.issued 2026 -
dc.identifier.uri https://scholar.dgist.ac.kr/handle/20.500.11750/59743 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000942916 -
dc.description Difluoromethylation, Ni-catalysis, Cross-coupling reaction, C(sp³)–CF₂H bond formation, Regioselective functionalization -
dc.description.tableofcontents Ⅰ. Introduction 1
1.1 Backgrounds 1
1.2 Previous studies 2
1.3 Our work 4
II. RESULTS AND DISCUSSIONS 6
2.1 Optimization of reaction conditions 6
2.2 Substrate scopes 12
2.2.1 Substrate scopes of Olefins 12
2.2.2 Substrate scopes of Alkyl halide 13
2.3 Asymmetric reaction 14
2.4 Future work 15
III. CONCLUSION 17
IV. EXPERIMENTAL SECTION 18
REFERENCE 29
국문 요약문 31		 -
dc.format.extent 31 -
dc.language eng -
dc.publisher DGIST -
dc.title Synthesis of CF₂H-Substituted Alkanes via NiH-Catalyzed Hydroalkylation of Unactivated Alkenes -
dc.title.alternative 니켈 하이드라이드 촉매하에서 비활성 알켄의 하이드로알킬화 반응을 통한 디플루오로메틸 치환 알케인 합성 -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000942916 -
dc.description.degree Master -
dc.contributor.department Department of Physics and Chemistry -
dc.date.awarded 2026-02-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.MM 심16 202602 -
dc.date.accepted 2026-01-19 -
dc.contributor.alternativeDepartment 화학물리학과 -
dc.subject.keyword Difluoromethylation, Ni-catalysis, Cross-coupling reaction, C(sp³)–CF₂H bond formation, Regioselective functionalization -
dc.contributor.affiliatedAuthor Gyuhwan Sim -
dc.contributor.affiliatedAuthor Sangwon Seo -
dc.contributor.alternativeName 심규환 -
dc.contributor.alternativeName Sangwon Seo -
dc.rights.embargoReleaseDate 2030-02-28 -
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