Title

Enantioconvergent Alkenylation of α-Halocarbonyl Compounds via NiH Catalysis: Straightforward Approach to α-Enantioenriched-β-Methylene Carbonyls

Alternative Title

니켈 하이드라이드 촉매를 이용한 알파-할로카보닐 화합물의 엔안티오컨버전트 알케닐화 반응 연구

DGIST Authors

Seji Jang ; Sangwon Seo

Advisor

서상원

Issued Date

2026

Awarded Date

2026-02-01

Type

Thesis

Description

Ni-catalyst, Regioselectivity, Enantioselectivity, Alkenylation, Alkyne

Table Of Contents

Ⅰ. INTRODUCTION 1
1.1 Backgrounds and previous studies 1
1.2 Our works 3
ⅠⅠ. RESULTS AND DISCUSSIONS 3
2.1 Enantioconvergent alkenylation of α-halocarbonyl compounds via NiH catalysis 3
2.1.1 Reaction Optimization 3
2.1.2 Substrate Scopes 13
2.1.3 Synthetic Application 14
2.1.4 Mechanism studies 16
ⅠⅠⅠ. CONCLUSION 19
ⅠV. EXPERIMENT SECTION 20
REFERENCE 49
국문요약문 52

URI

https://scholar.dgist.ac.kr/handle/20.500.11750/59746
http://dgist.dcollection.net/common/orgView/200000947564

DOI

10.22677/THESIS.200000947564

Degree

Master

Department

Department of Physics and Chemistry

Publisher

DGIST

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