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  Department of Physics and Chemistry Theses Ph.D.

Practical Deuteration of Organic Compounds by Thiyl Radical Catalysis

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dc.contributor.advisor 이성기 -
dc.contributor.author Jiin Lee -
dc.date.accessioned 2026-01-23T11:00:41Z -
dc.date.available 2026-01-23T11:00:41Z -
dc.date.issued 2025 -
dc.identifier.uri https://scholar.dgist.ac.kr/handle/20.500.11750/59801 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000891848 -
dc.description deuteration, thiyl radical, hydrogen atom transfer, halogen atom transfer -
dc.description.tableofcontents Abstract i
List of Contents ii
Ⅰ. Chapter 1. Dehalogenative deuteration of alkyl and aryl bromides by thiyl radical catalysis
1. Introduction 1
2. Result & discussion 4
2.1 Reaction optimization 4
2.2 Control experiment 7
2.3 Substate scope 7
2.4 Mechanistic study 10
2.5 Synthetic utility 11
3. Conclusion 13
4. Experimental data 14
4.1 General consideration 14
4.2 Experimental section 15
4.3 UV/Vis absorption spectroscopy 43
5. References 48
Ⅱ. Chapter 2. Decarbonylative iterative deuteration of alkyl aldehydes by thiyl radical catalysis
1. Introduction 52
2. Result & discussion 55
2.1 Reaction optimization 55
2.2 Substate scope 61
2.3 Synthetic application 62
3. Conclusion 65
4. Experimental data 66
4.1 General consideration 66
4.2 Experimental section 67
5. References 76
요약문 79		 -
dc.format.extent 79 -
dc.language eng -
dc.publisher DGIST -
dc.title Practical Deuteration of Organic Compounds by Thiyl Radical Catalysis -
dc.title.alternative 황 중심 라디칼 촉매를 이용한 유기 화합물의 실용적 중수소화 -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000891848 -
dc.description.degree Doctor -
dc.contributor.department Department of Physics and Chemistry -
dc.contributor.coadvisor Byunghyuck Jung -
dc.date.awarded 2025-08-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.MD 이78 202508 -
dc.date.accepted 2025-07-21 -
dc.contributor.alternativeDepartment 화학물리학과 -
dc.subject.keyword deuteration, thiyl radical, hydrogen atom transfer, halogen atom transfer -
dc.contributor.affiliatedAuthor Jiin Lee -
dc.contributor.affiliatedAuthor Sunggi Lee -
dc.contributor.affiliatedAuthor Byunghyuck Jung -
dc.contributor.alternativeName 이지인 -
dc.contributor.alternativeName Sunggi Lee -
dc.contributor.alternativeName 정병혁 -
dc.rights.embargoReleaseDate 2027-08-31 -
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