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  Department of Physics and Chemistry Theses Master

Earth-Abundant Transition Metal-Catalyzed Regioselective Hydrosilylation of Allenes

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dc.contributor.advisor 정병혁 -
dc.contributor.author Seongha Kim -
dc.date.accessioned 2026-01-23T11:03:29Z -
dc.date.available 2026-01-23T11:03:29Z -
dc.date.issued 2025 -
dc.identifier.uri https://scholar.dgist.ac.kr/handle/20.500.11750/59848 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000889871 -
dc.description Allene, Protosilylation, Hydrosilylation, Allylsilanes, Cu-catalyst, Ni-catalyst, On-water -
dc.description.tableofcontents ABSTRACT i
LIST OF CONTENTS ii

Ⅰ. INTRODUCTION 1
1.1 Backgrounds and previous studies 1
1.2 Our works 1
ⅠⅠ. RESULTS AND DISCUSSIONS 2
2.1 Cu-catalyzed protosilyaltion of allenes. 2
2.1.1 Reaction Optimization 2
2.1.1.1 Optimization for protosilylation of mono-substituted allene 2
2.1.1.2 Optimization for protosilylation under on-water conditions 7
2.1.2 Substrate Scopes 8
2.1.2.1 Substrate scopes for protosilylation of mono-substituted allene 8
2.1.2.2 Substrate scopes for protosilylation under on-water conditions 9
2.1.3 Mechanistic Studies 10
2.1.4 Synthetic application 13
2.2 Ni-catalyzed hydrosilyaltion of allenes. 14
2.2.1 Reaction Optimization 14
2.2.2 Substrate Scopes 17
2.2.3 Mechanistic Studies 18
III. CONCLUSION 21
IV. EXPERIMENTAL SECTION 22
REFERENCE 57
국문 요약문 61		 -
dc.format.extent 61 -
dc.language eng -
dc.publisher DGIST -
dc.title Earth-Abundant Transition Metal-Catalyzed Regioselective Hydrosilylation of Allenes -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000889871 -
dc.description.degree Master -
dc.contributor.department Department of Physics and Chemistry -
dc.contributor.coadvisor Sangwon Seo -
dc.date.awarded 2025-08-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.MM 김54 202508 -
dc.date.accepted 2025-07-21 -
dc.contributor.alternativeDepartment 화학물리학과 -
dc.subject.keyword Allene, Protosilylation, Hydrosilylation, Allylsilanes, Cu-catalyst, Ni-catalyst, On-water -
dc.contributor.affiliatedAuthor Seongha Kim -
dc.contributor.affiliatedAuthor Byunghyuck Jung -
dc.contributor.affiliatedAuthor Sangwon Seo -
dc.contributor.alternativeName 김성하 -
dc.contributor.alternativeName Byunghyuck Jung -
dc.contributor.alternativeName 서상원 -
dc.rights.embargoReleaseDate 2026-08-31 -
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