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  Department of Physics and Chemistry Theses Master

In Situ Synthesis of Metalloporphyrin Metal–Organic Frameworks via Porphyrinic Core Activation

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dc.contributor.advisor 박진희 -
dc.contributor.author Sujeong Yu -
dc.date.accessioned 2026-09-01T19:33:59Z -
dc.date.available 2026-09-01T19:33:59Z -
dc.date.issued 2026 -
dc.identifier.uri https://scholar.dgist.ac.kr/handle/20.500.11750/60830 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200001014839 -
dc.description Metal–organic frameworks, Metalloporphyrin MOFs, In situ metalation, Porphyrin core metalation -
dc.description.tableofcontents List of Contents
Abstract i
List of contents ⅱ
List of figures ⅳ
List of schemes ⅵi

I. Introduction 1
II. Experimental Methods
2.1 Materials 5
2.2 Measurements 6
2.3 Syntheses 6
2.3.1 Synthesis of TCPP 6
2.3.2 Synthesis of CoCa-TCPP-I 9
2.3.3 Synthesis of CoCa-TCPP-II 9
2.3.4 Synthesis of Fe-TCPP-I 9
2.3.5 Synthesis of Fe-TCPP-II 9
III. Results and Discussions
3.1 Co–Ca Metalloporphyrin Frameworks 10
3.1.1 Synthesis and crystal structure of CoCa-TCPP-I 10
3.1.2 Synthesis and crystal structure of CoCa-TCPP-II 17
3.1.3 Solvent stability test of Co–Ca Metalloporphyrin Frameworks 19
3.1.4 Comparison of CoCa-TCPP-I and CoCa-TCPP-II 21
3.2 Iron-Based Metalloporphyrin Frameworks 23
3.2.1 Design and Crystal Structure of Fe-TCPP-I 23
3.2.2 Exfoliation Strategy and Morphological Impact 25
3.2.3 Synthesis and Exfoliation of Fe-TCPP-II 28
3.2.4 Structural Characterization of Fe-TCPP Frameworks 32
3.2.5 Water stability test of Fe-TCPP 34
3.2.6 Catalytic activity 37
Ⅳ. References 40
Ⅴ. Summary 45		 -
dc.format.extent 45 -
dc.language eng -
dc.publisher DGIST -
dc.title In Situ Synthesis of Metalloporphyrin Metal–Organic Frameworks via Porphyrinic Core Activation -
dc.title.alternative 포르피린 중심부 활성화를 통한 금속포르피린 형성과 금속-유기 구조체의 동시 합성 -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200001014839 -
dc.description.degree Master -
dc.contributor.department Department of Physics and Chemistry -
dc.date.awarded 2026-08-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.MM 유56 202608 -
dc.date.accepted 2026-07-21 -
dc.contributor.alternativeDepartment 화학물리학과 -
dc.subject.keyword Metal–organic frameworks, Metalloporphyrin MOFs, In situ metalation, Porphyrin core metalation -
dc.contributor.affiliatedAuthor Sujeong Yu -
dc.contributor.affiliatedAuthor Jinhee Park -
dc.contributor.alternativeName 유수정 -
dc.contributor.alternativeName Jinhee Park -
dc.rights.embargoReleaseDate 2031-08-31 -
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