Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Pereira, Marcelo Maciel | - |
dc.contributor.author | Gomes, Elisa Silva | - |
dc.contributor.author | Silva, Alessandra Vieira | - |
dc.contributor.author | Pinar, Ana Belen | - |
dc.contributor.author | Willinger, Marc-Georg. | - |
dc.contributor.author | Shanmugam, Sangaraju | - |
dc.contributor.author | Chizallet, Celine | - |
dc.contributor.author | Laugel, Guillaume | - |
dc.contributor.author | Losch, Pit | - |
dc.contributor.author | Louis, Benoˆıt | - |
dc.date.accessioned | 2018-08-29T05:52:57Z | - |
dc.date.available | 2018-08-29T05:52:57Z | - |
dc.date.created | 2018-08-29 | - |
dc.date.issued | 2018-08 | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/9244 | - |
dc.description.abstract | A family of Al-rich ZSM-5 zeolites with Si/Al = 8 ± 0.5 was prepared according to a biomass-mediated supramolecular approach. A combination of advanced characterisation techniques and periodic density functional theory (DFT) calculations unraveled the purity and stability of un-expected Al-enriched ZSM-5 structures, hence allowing to cross the frontier of Si/Al lower limit. In addition, these Al-rich ZSM-5 zeolites demonstrated high catalytic activity in n-hexane cracking and methanol conversion into hydrocarbons, being in line with the presence of numerous Brønsted acid sites. © 2018 The Royal Society of Chemistry. | - |
dc.language | English | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | Biomass-mediated ZSM-5 zeolite synthesis: When self-assembly allows to cross the Si/Al lower limit | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c8sc01675e | - |
dc.identifier.scopusid | 2-s2.0-85051254879 | - |
dc.identifier.bibliographicCitation | Chemical Science, v.9, no.31, pp.6532 - 6539 | - |
dc.description.isOpenAccess | TRUE | - |
dc.subject.keywordPlus | BRONSTED ACID SITES | - |
dc.subject.keywordPlus | SUPRAMOLECULAR CHEMISTRY | - |
dc.subject.keywordPlus | SILICA NANOPARTICLES | - |
dc.subject.keywordPlus | BASIC SOLUTIONS | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | STABILITY | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | FRAMEWORK | - |
dc.subject.keywordPlus | ALUMINUM | - |
dc.citation.endPage | 6539 | - |
dc.citation.number | 31 | - |
dc.citation.startPage | 6532 | - |
dc.citation.title | Chemical Science | - |
dc.citation.volume | 9 | - |