Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jeong, Donghyun | ko |
dc.contributor.author | Ohta, Takehiro | ko |
dc.contributor.author | Cho, Jaeheung | ko |
dc.date.accessioned | 2019-01-16T14:56:11Z | - |
dc.date.available | 2019-01-16T14:56:11Z | - |
dc.date.created | 2018-12-07 | - |
dc.date.issued | 2018-11 | - |
dc.identifier.citation | Journal of the American Chemical Society, v.140, no.47, pp.16037 - 16041 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/9494 | - |
dc.description.abstract | Transition metal-iodosylarene complexes have been proposed to be key intermediates in the catalytic cycles of metal catalysts with iodosylarene. We report the first X-ray crystal structure and spectroscopic characterization of a mononuclear nonheme manganese(III)-iodosylarene complex with a tetradentate macrocyclic ligand, [MnIII(TBDAP)(OIPh)(OH)]2+ (2). The manganese(III)-iodosylarene complex is capable of conducting various oxidation reactions with organic substrates, such as C-H bond activation, sulfoxidation and epoxidation. Kinetic studies including isotope labeling experiments and Hammett correlation demonstrate the electrophilic character on the Mn-iodosylarene adduct. This novel intermediate would be prominently valuable for expanding the chemistry of transition metal catalysts. Copyright © 2018 American Chemical Society. | - |
dc.language | English | - |
dc.publisher | American Chemical Society | - |
dc.title | Structure and Reactivity of a Mononuclear Nonheme Manganese(III)-Iodosylarene Complex | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/jacs.8b10244 | - |
dc.identifier.wosid | 000451933100010 | - |
dc.identifier.scopusid | 2-s2.0-85057269910 | - |
dc.type.local | Article(Overseas) | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.contributor.nonIdAuthor | Ohta, Takehiro | - |
dc.identifier.citationVolume | 140 | - |
dc.identifier.citationNumber | 47 | - |
dc.identifier.citationStartPage | 16037 | - |
dc.identifier.citationEndPage | 16041 | - |
dc.identifier.citationTitle | Journal of the American Chemical Society | - |
dc.type.journalArticle | Article | - |
dc.description.isOpenAccess | N | - |
dc.subject.keywordPlus | MULTIPLE ACTIVE OXIDANTS | - |
dc.subject.keywordPlus | DIOXYGEN ACTIVATION | - |
dc.subject.keywordPlus | HYPERVALENT IODINE | - |
dc.subject.keywordPlus | OXYGEN-TRANSFER | - |
dc.subject.keywordPlus | ATOM TRANSFER | - |
dc.subject.keywordPlus | IRON | - |
dc.subject.keywordPlus | EPOXIDATION | - |
dc.subject.keywordPlus | MANGANESE | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | IRON(III) | - |
dc.contributor.affiliatedAuthor | Cho, Jaeheung | - |
There are no files associated with this item.