Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kuruppathparambil, Roshith Roshan | ko |
dc.contributor.author | Babu, Robin | ko |
dc.contributor.author | Jeong, Hochan | ko |
dc.contributor.author | Jang, Yun Hee | ko |
dc.contributor.author | Lee, Mi Hye | ko |
dc.contributor.author | Park, Dae-Won | ko |
dc.date.accessioned | 2019-05-28T04:23:09Z | - |
dc.date.available | 2019-05-28T04:23:09Z | - |
dc.date.created | 2019-05-14 | - |
dc.date.issued | 2019-05 | - |
dc.identifier.citation | Korean Journal of Chemical Engineering, v.36, no.5, pp.643 - 649 | - |
dc.identifier.issn | 0256-1115 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/9852 | - |
dc.description.abstract | Vanadium containing 3D MOF, MIL-47 displayed excellent synergistic catalysis with alkyl ammonium halides (TBAX) in the room temperature fixation of CO 2 . Theoretical intrinsic-reaction-coordinate calculations were performed at the level of M06/LACVP**++ implemented in Jaguar v8.5 software to ascertain the mechanistic pathways of catalysis. A homogeneous complex of vanadium, vanadium acetyl acetonato [VO(acac) 2 ], was used as a model system to investigate the mechanism behind the synergistic activity of the MIL-47/TBAX, which indeed shows that the activation energy of the CO 2 fixation is considerably lowered by about 30–35 kcal compared to the uncatalyzed reactions. © 2019, The Korean Institute of Chemical Engineers. | - |
dc.language | English | - |
dc.publisher | 한국화학공학회 | - |
dc.title | Room temperature CO2 fixation via cyclic carbonate synthesis over vanadium-MOF catalysts | - |
dc.type | Article | - |
dc.identifier.doi | 10.1007/s11814-019-0255-5 | - |
dc.identifier.wosid | 000467475500001 | - |
dc.identifier.scopusid | 2-s2.0-85065698793 | - |
dc.type.local | Article(Overseas) | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.identifier.kciid | ART002462607 | - |
dc.contributor.nonIdAuthor | Kuruppathparambil, Roshith Roshan | - |
dc.contributor.nonIdAuthor | Babu, Robin | - |
dc.contributor.nonIdAuthor | Jeong, Hochan | - |
dc.contributor.nonIdAuthor | Lee, Mi Hye | - |
dc.contributor.nonIdAuthor | Park, Dae-Won | - |
dc.identifier.citationVolume | 36 | - |
dc.identifier.citationNumber | 5 | - |
dc.identifier.citationStartPage | 643 | - |
dc.identifier.citationEndPage | 649 | - |
dc.identifier.citationTitle | Korean Journal of Chemical Engineering | - |
dc.type.journalArticle | Article | - |
dc.description.isOpenAccess | N | - |
dc.subject.keywordAuthor | DFT | - |
dc.subject.keywordAuthor | MIL-47/TBAB | - |
dc.subject.keywordAuthor | CO2 | - |
dc.subject.keywordAuthor | Epoxide | - |
dc.subject.keywordAuthor | Cyclic Carbonate | - |
dc.subject.keywordPlus | MICROWAVE-ASSISTED SYNTHESIS | - |
dc.subject.keywordPlus | CHEMICAL FIXATION | - |
dc.subject.keywordPlus | STYRENE CARBONATE | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | DIOXIDE | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | TRANSFORMATION | - |
dc.subject.keywordPlus | EPOXIDES | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORK | - |
dc.subject.keywordPlus | EFFICIENT HETEROGENEOUS CATALYST | - |
dc.contributor.affiliatedAuthor | Jang, Yun Hee | - |
There are no files associated with this item.