Synthesis, Characterization and Reactivity of a High-valent Manganese-oxygen Complex with a Me3-TPADP ligand
- Title
- Synthesis, Characterization and Reactivity of a High-valent Manganese-oxygen Complex with a Me3-TPADP ligand
- Author(s)
- Youngchae Jang
- DGIST Authors
- Cho, Jaeheung ; Jang, Youngchae ; Koo, JaeHyung
- Advisor
- 조재흥
- Co-Advisor(s)
- JaeHyung Koo
- Issued Date
- 2019
- Awarded Date
- 2019-02
- Type
- Thesis
- Table Of Contents
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Abstract i
List of contents ii
List of tables iv
List of figures v
Ⅰ. Introduction
I. Introdiction 1
II. Experimental section
2.1 Materials and Instrumentation 3
2.2 Synthesis of Manganese complexes 4
2.2.1 [MnII(Me3-TPADP)(OTf)2] (1) 4
2.2.2 [MnIV(Me3-TPADP)(OH)(OCH3)]2+ (2) 5
2.2.3 [MnIV(Me3-TPADP)(OH)(OC2H5)]2+ (3) 5
2.2.4 [MnIV(Me3-TPADP)(OH)(OC3H7)]2+ (4) 6
2.3 Magnetic measurement 6
2.4 X-ray crystallography 7
2.5 Reactivity 10
III. Results and discussion
3.1 Synthesis of Manganese(II)-Starting Complex 10
3.2 Synthesis of Manganese(IV)-Hydroxo Complexes 13
3.3 Characterization of [MnIV(Me3-TPADP)(OH)(OCH3)]2+ (2) 13
3.4 Characterization of [MnIV(Me3-TPADP)(OH)(OC2H5)]2+ (3) 17
3.5 Characterization of [MnIV(Me3-TPADP)(OH)(OC3H7)]2+ (4) 19
3.6 Reactivity 24
3.7 Comparison of cis-effect between 2, 3 and 4 28
IV. Conclusion
4.1 Conclusion 29
- URI
-
http://dgist.dcollection.net/common/orgView/200000171460
http://hdl.handle.net/20.500.11750/10714
- Degree
- MASTER
- Department
- Emerging Materials Science
- Publisher
- DGIST
- Related Researcher
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Koo, JaeHyung
- Research Interests 장내미생물/감염균 유래 대사체를 통한 신경염증; 알츠하이머병; 우울증; 당뇨/비만; 대사체/수용체 상호작용에 의한 대사연구
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- Files in This Item:
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- Appears in Collections:
- Department of Physics and Chemistry Theses Master
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