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Synthesis, Characterization and Reactivity of a High-valent Manganese-oxygen Complex with a Me3-TPADP ligand

Title
Synthesis, Characterization and Reactivity of a High-valent Manganese-oxygen Complex with a Me3-TPADP ligand
Authors
Youngchae Jang
DGIST Authors
Jang, Youngchae; Koo, JaeHyung; Cho, Jaeheung
Advisor(s)
조재흥
Co-Advisor(s)
JaeHyung Koo
Issue Date
2019
Available Date
2019-10-03
Degree Date
2019-02
Type
Thesis
Table Of Contents
Abstract i List of contents ii List of tables iv List of figures v Ⅰ. Introduction I. Introdiction 1 II. Experimental section 2.1 Materials and Instrumentation 3 2.2 Synthesis of Manganese complexes 4 2.2.1 [MnII(Me3-TPADP)(OTf)2] (1) 4 2.2.2 [MnIV(Me3-TPADP)(OH)(OCH3)]2+ (2) 5 2.2.3 [MnIV(Me3-TPADP)(OH)(OC2H5)]2+ (3) 5 2.2.4 [MnIV(Me3-TPADP)(OH)(OC3H7)]2+ (4) 6 2.3 Magnetic measurement 6 2.4 X-ray crystallography 7 2.5 Reactivity 10 III. Results and discussion 3.1 Synthesis of Manganese(II)-Starting Complex 10 3.2 Synthesis of Manganese(IV)-Hydroxo Complexes 13 3.3 Characterization of [MnIV(Me3-TPADP)(OH)(OCH3)]2+ (2) 13 3.4 Characterization of [MnIV(Me3-TPADP)(OH)(OC2H5)]2+ (3) 17 3.5 Characterization of [MnIV(Me3-TPADP)(OH)(OC3H7)]2+ (4) 19 3.6 Reactivity 24 3.7 Comparison of cis-effect between 2, 3 and 4 28 IV. Conclusion 4.1 Conclusion 29
URI
http://dgist.dcollection.net/common/orgView/200000171460
http://hdl.handle.net/20.500.11750/10714
DOI
10.22677/thesis.200000171460
Degree
MASTER
Department
Emerging Materials Science
University
DGIST
Related Researcher
  • Author Koo, JaeHyung Ectopic Odorant Receptor Lab
  • Research Interests 장내미생물/감염균 유래 대사체를 통한 신경염증, 알츠하이머병, 우울증, 당뇨/비만, 대사체/수용체 상호작용에 의한 대사연구
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Collection:
Department of Emerging Materials ScienceThesesMaster


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