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Oxygen-vacancy-endurable conductors with enhanced transparency using correlated 4d2 SrMoO3 Thin Films

Title
Oxygen-vacancy-endurable conductors with enhanced transparency using correlated 4d2 SrMoO3 Thin Films
Author(s)
Ha, YoungkyoungLee, Shinbuhm
Issued Date
2020-07
Citation
Advanced Functional Materials, v.30, no.28, pp.2001489
Type
Article
Author Keywords
correlated metalSrMoO3transparent conductor
Keywords
ELECTRICAL-PROPERTIESMETAL
ISSN
1616-301X
Abstract
Degenerately doped wide-bandgap semiconductors, e.g., Sn-doped In2O3, are the most conventional transparent conductors (TCs), but degradation of the TC performance by a doping bottleneck or instability due to oxygen vacancies is encountered. Recently, nondoped correlated metals have attracted great attention as a new strategy for developing next-generation TCs. To date, most studies of this brand-new type of TC have been biased toward 3d1 vanadates. Here, compared with 3d1 SrVO3, it is found that the 4d2 SrMoO3 thin films show promising TC properties: higher ultraviolet–visible transmittance of 80% and extremely low resistivity of 100 µΩ cm at room temperature. This enhancement in the SrMoO3 is ascribed to a p-4d transition occurring at higher photon energy and a higher number of electrons in the outermost 4d orbitals, respectively. In addition, the TC properties of the correlated SrMoO3 are resistive to oxygen vacancies. Using spectroscopic ellipsometry, it is found that this robustness is attributed to the lack of formation of defect states near the Fermi level, which is different from the observation in conventional TCs. Taken together, the correlated 4d2 SrMoO3 is appealing for next-generation oxygen-vacancy-endurable conductors with enhanced transparency. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
http://hdl.handle.net/20.500.11750/12062
DOI
10.1002/adfm.202001489
Publisher
John Wiley & Sons, Inc.
Related Researcher
  • 이신범 Lee, Shinbuhm
  • Research Interests Multifunctional films; Experimental condensed matter physics
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Department of Physics and Chemistry Multifunctional films and nanostructures Lab 1. Journal Articles

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