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Carbide composite nanowire as bifunctional electrocatalyst for lithium oxygen batteries

Title
Carbide composite nanowire as bifunctional electrocatalyst for lithium oxygen batteries
Author(s)
Christy, MariaArul, AnupriyaKim, Young-Beom
Issued Date
2019-03
Type
Article
Article Type
Article
Author Keywords
Bifunctional catalystCarbideLi–O2 batteryNanowireOxygen evolution reactionOxygen reduction reaction
Keywords
BIMETALLIC CARBIDEHYDROGEN EVOLUTIONTUNGSTEN CARBIDEMETAL CARBIDESCATHODEREDUCTIONEFFICIENTCATALYSTSOLVENTSNITRIDE
ISSN
0013-4686
Abstract
Producing low–cost non–precious metal catalysts in large scales to be used as air–cathodes for efficient oxygen reduction and evolution reactions in Li–O2 batteries is a demanding task. Herein, we report a simple technique for the synthesis of a carbide composite comprising molybdenum and tungsten with a robust nanowire structure. When applied as an air–cathode electrocatalyst in Li–O2 batteries, the nanowire composite delivered high specific discharge capacity with reversibility and cyclability. This work provides a novel approach for tailoring nano–architectures and thereby achieving high–power Li–air batteries. © 2019 Elsevier Ltd
URI
http://hdl.handle.net/20.500.11750/12945
DOI
10.1016/j.electacta.2019.01.099
Publisher
Pergamon Press Ltd.
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