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Hydride-Transfer Reaction to a Mononuclear Manganese(III) Iodosylarene Complex

Title
Hydride-Transfer Reaction to a Mononuclear Manganese(III) Iodosylarene Complex
Authors
Jeong, DonghyunCho, Jaeheung
DGIST Authors
Jeong, Donghyun; Cho, Jaeheung
Issue Date
2021-06
Citation
Inorganic Chemistry, 60(11), 7612-7616
Type
Article
Keywords
ELECTRON-TRANSFERNADH ANALOGSOXIDATIONS
ISSN
0020-1669
Abstract
Metal iodosylarene species have received interest because of their potential oxidative power as a catalyst. We present the first example of hydride-transfer reactions to a mononuclear manganese(III) iodosylbenzene complex, [MnIII(TBDAP)(OIPh)(OH)]2+ (1; TBDAP = N,N-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane), with dihydronicotinamide adenine dinucleotide (NADH) analogues. Kinetic studies show that hydride-transfer from the NADH analogues to 1 occurs via a proton-coupled electron transfer, followed by a rapid electron transfer. © 2021 American Chemical Society.
URI
http://hdl.handle.net/20.500.11750/15435
DOI
10.1021/acs.inorgchem.1c00562
Publisher
American Chemical Society
Files:
There are no files associated with this item.
Collection:
Department of Physics and ChemistryBiomimetic Materials Laboratory1. Journal Articles


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