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Hydride-Transfer Reaction to a Mononuclear Manganese(III) Iodosylarene Complex

Title
Hydride-Transfer Reaction to a Mononuclear Manganese(III) Iodosylarene Complex
Author(s)
Jeong, DonghyunCho, Jaeheung
Issued Date
2021-06
Citation
Inorganic Chemistry, v.60, no.11, pp.7612 - 7616
Type
Article
Keywords
OXIDATIONSNADH ANALOGSELECTRON-TRANSFER
ISSN
0020-1669
Abstract
Metal iodosylarene species have received interest because of their potential oxidative power as a catalyst. We present the first example of hydride-transfer reactions to a mononuclear manganese(III) iodosylbenzene complex, [MnIII(TBDAP)(OIPh)(OH)]2+ (1; TBDAP = N,N-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane), with dihydronicotinamide adenine dinucleotide (NADH) analogues. Kinetic studies show that hydride-transfer from the NADH analogues to 1 occurs via a proton-coupled electron transfer, followed by a rapid electron transfer. © 2021 American Chemical Society.
URI
http://hdl.handle.net/20.500.11750/15435
DOI
10.1021/acs.inorgchem.1c00562
Publisher
American Chemical Society
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Department of Physics and Chemistry Biomimetic Materials Laboratory 1. Journal Articles

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