Hydride-Transfer Reaction to a Mononuclear Manganese(III) Iodosylarene Complex
- Title
- Hydride-Transfer Reaction to a Mononuclear Manganese(III) Iodosylarene Complex
- Author(s)
- Jeong, Donghyun ; Cho, Jaeheung
- Issued Date
- 2021-06
- Citation
- Inorganic Chemistry, v.60, no.11, pp.7612 - 7616
- Type
- Article
- Keywords
- OXIDATIONS ; NADH ANALOGS ; ELECTRON-TRANSFER
- ISSN
- 0020-1669
- Abstract
- Metal iodosylarene species have received interest because of their potential oxidative power as a catalyst. We present the first example of hydride-transfer reactions to a mononuclear manganese(III) iodosylbenzene complex, [MnIII(TBDAP)(OIPh)(OH)]2+ (1; TBDAP = N,N-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane), with dihydronicotinamide adenine dinucleotide (NADH) analogues. Kinetic studies show that hydride-transfer from the NADH analogues to 1 occurs via a proton-coupled electron transfer, followed by a rapid electron transfer. © 2021 American Chemical Society.
- Publisher
- American Chemical Society
- Files in This Item:
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- Appears in Collections:
- Department of Physics and Chemistry Biomimetic Materials Laboratory 1. Journal Articles
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