Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Jeong, Donghyun | - |
| dc.contributor.author | Cho, Jaeheung | - |
| dc.date.accessioned | 2021-10-07T12:00:13Z | - |
| dc.date.available | 2021-10-07T12:00:13Z | - |
| dc.date.created | 2021-06-14 | - |
| dc.date.issued | 2021-06 | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/20.500.11750/15435 | - |
| dc.description.abstract | Metal iodosylarene species have received interest because of their potential oxidative power as a catalyst. We present the first example of hydride-transfer reactions to a mononuclear manganese(III) iodosylbenzene complex, [MnIII(TBDAP)(OIPh)(OH)]2+ (1; TBDAP = N,N-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane), with dihydronicotinamide adenine dinucleotide (NADH) analogues. Kinetic studies show that hydride-transfer from the NADH analogues to 1 occurs via a proton-coupled electron transfer, followed by a rapid electron transfer. © 2021 American Chemical Society. | - |
| dc.language | English | - |
| dc.publisher | American Chemical Society | - |
| dc.title | Hydride-Transfer Reaction to a Mononuclear Manganese(III) Iodosylarene Complex | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1021/acs.inorgchem.1c00562 | - |
| dc.identifier.scopusid | 2-s2.0-85106390741 | - |
| dc.identifier.bibliographicCitation | Inorganic Chemistry, v.60, no.11, pp.7612 - 7616 | - |
| dc.description.isOpenAccess | FALSE | - |
| dc.subject.keywordPlus | ELECTRON-TRANSFER | - |
| dc.subject.keywordPlus | NADH ANALOGS | - |
| dc.subject.keywordPlus | OXIDATIONS | - |
| dc.citation.endPage | 7616 | - |
| dc.citation.number | 11 | - |
| dc.citation.startPage | 7612 | - |
| dc.citation.title | Inorganic Chemistry | - |
| dc.citation.volume | 60 | - |
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