Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Shin, Dong Ok | - |
dc.contributor.author | Kim, Hyungjun | - |
dc.contributor.author | Choi, Jaecheol | - |
dc.contributor.author | Kim, Min Pyeong | - |
dc.contributor.author | Kim, Ju Young | - |
dc.contributor.author | Kang, Seok Hun | - |
dc.contributor.author | Park, Young-Sam | - |
dc.contributor.author | Hong, Sung You | - |
dc.contributor.author | Cho, Maenghyo | - |
dc.contributor.author | Lee, Young-Gi | - |
dc.contributor.author | Cho, Kyeongjae | - |
dc.contributor.author | Lee, Yong Min | - |
dc.date.accessioned | 2022-10-31T06:30:00Z | - |
dc.date.available | 2022-10-31T06:30:00Z | - |
dc.date.created | 2022-06-16 | - |
dc.date.issued | 2022-08 | - |
dc.identifier.issn | 2405-8297 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/16965 | - |
dc.description.abstract | Electrodes supported by conductive binders are expected to outperform ones with inert binders that potentially disturb electronic/ionic contacts at interfaces. Unlike electron-conductive binders, the employment of Li+ conductive binders has attracted relatively little attention due to the liquid electrolyte (LE)-impregnated electrode configuration in the conventional lithium-ion batteries (LIBs). Herein, an all-solid-state electrolyte-free electrode where electrolyte components are completely excluded is introduced as a new tactical electrode construction to evaluate the effectiveness of the Li+-conductive binder on enhancing the interfacial conduction, ultimately leading to high-performance all-solid-state batteries (ASSBs). Conductive lithium carboxymethyl cellulose (Li-CMC) is prepared through an optimized two-step cation-exchange reaction without physical degradation. The electrolyte-free graphite electrode employing Li-CMC as the binder shows strikingly improved areal and volumetric capacity of 1.46 mAh cm(-2) and 490 mAh cm(-3) at a high current rate (1.91 mA cm(-2)) and 60 C which are far superior to those (1.07 mAh cm(-2) and 356.7 mAh cm(-3)) using Na-CMC. Moreover, systematic monitoring of the lithiation dynamics inside the electrolyte-free electrode clarifies that the interfacial Li+ conduction is greatly promoted in the Li-CMC electrode. Complementary analysis from in-depth electrochemical measurements and multiscale simulations verifies that serious internal resistance from impeded interparticle diffusion by inert binders can be substantially mitigated using Li-CMC. | - |
dc.language | English | - |
dc.publisher | Elsevier BV | - |
dc.title | Electrolyte-free graphite electrode with enhanced interfacial conduction using Li+-conductive binder for high-performance all-solid-state batteries | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.ensm.2022.04.029 | - |
dc.identifier.wosid | 000798010600002 | - |
dc.identifier.scopusid | 2-s2.0-85129130495 | - |
dc.identifier.bibliographicCitation | Energy Storage Materials, v.49, pp.481 - 492 | - |
dc.description.isOpenAccess | TRUE | - |
dc.subject.keywordAuthor | interfacial conduction | - |
dc.subject.keywordAuthor | all-solid-state battery electrode | - |
dc.subject.keywordAuthor | carboxymethyl cellulose | - |
dc.subject.keywordAuthor | Li+-conductive binder | - |
dc.subject.keywordPlus | LITHIATION | - |
dc.subject.keywordPlus | VISCOSITY | - |
dc.subject.keywordPlus | TOTAL-ENERGY CALCULATIONS | - |
dc.subject.keywordPlus | CARBOXYMETHYL CELLULOSE | - |
dc.subject.keywordPlus | AB-INITIO | - |
dc.subject.keywordPlus | POLYMERIC BINDERS | - |
dc.subject.keywordPlus | SILICON ANODES | - |
dc.subject.keywordPlus | LITHIUM | - |
dc.citation.endPage | 492 | - |
dc.citation.startPage | 481 | - |
dc.citation.title | Energy Storage Materials | - |
dc.citation.volume | 49 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.type.docType | Article | - |
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