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A ruthenium complex as a single-component redox shuttle for electrochemical photovoltaics

Title
A ruthenium complex as a single-component redox shuttle for electrochemical photovoltaics
Author(s)
Kim, Jeung YoonYun, Won SeokSon, Ho-JinLee, JaeDongJeong, Nak Cheon
Issued Date
2015-05
Citation
Chemical Communications, v.51, no.36, pp.7745 - 7748
Type
Article
Keywords
SENSITIZED SOLAR-CELLSELECTRON-TRANSFER MEDIATORSATOMIC LAYER DEPOSITIONPHOTOELECTROCHEMICAL CELLTITANIUM-DIOXIDETIO2 ELECTRODESMASS-TRANSPORTEFFICIENCYCHEMILUMINESCENCERESONANCE
ISSN
1359-7345
Abstract
A primitive version of a ruthenium complex [Ru(bpy)32+] was employed for the first time as a new conceptual "single-component redox shuttle" for dye-sensitized solar cells. This single shuttle led to a large enhancement of the open-circuit photovoltage (VOC) to ∼940 mV relative to that of conventional iodine-based shuttle and greatly increased the efficiency of the solar-to-electric energy conversion at lower illumination levels by a factor of ca. 5.6. © The Royal Society of Chemistry.
URI
http://hdl.handle.net/20.500.11750/2633
DOI
10.1039/c4cc09557j
Publisher
Royal Society of Chemistry
Related Researcher
  • 이재동 Lee, JaeDong
  • Research Interests Theoretical Condensed Matter Physics; Ultrafast Dynamics and Optics; Nonequilibrium Phenomena
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Appears in Collections:
Department of Physics and Chemistry Light and Matter Theory Laboratory 1. Journal Articles
Division of Nanotechnology 1. Journal Articles
Department of Physics and Chemistry Supramolecular Inorganic Chemistry Laboratory 1. Journal Articles

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