Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Son, Jung Su | - |
dc.contributor.author | Lim, Sung Chul | - |
dc.contributor.author | Lee, Ho Chun | - |
dc.contributor.author | Hong, Seung Tae | - |
dc.date.available | 2017-07-11T06:11:14Z | - |
dc.date.created | 2017-04-20 | - |
dc.date.issued | 2015-06 | - |
dc.identifier.issn | 2056-9890 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/2956 | - |
dc.description.abstract | In the structure of the title salt, [Co(C6H6N2)2(H2O)2](BF4)2, the CoII atom is located on an inversion centre. The transition metal is in a slightly distorted octahedral coordination environment, defined by the cyano N atoms of four hex-3-enedinitrile ligands in equatorial positions and the O atoms of two water molecules in axial positions. The bridging mode of the hex-3-enedinitrile ligands leads to the formation of cationic chains extending parallel to [110]. The BF4- counter-anion is disordered over two sets of sites [occupancy ratio = 0.512 (19):0.489 (19)]. It is located in the voids between the cationic chains and is connected to the aqua ligands of the latter through O-H⋯F hydrogen bonds. One methylene H atom of the hex-3-enedinitrile ligand forms another and weak C-H⋯O hydrogen bond with a water O atom of a neighbouring chain, thus consolidating the three-dimensional network structure. | - |
dc.language | English | - |
dc.publisher | International Union of Crystallography | - |
dc.title | Crystal structure of catena-poly[[[diaquacobalt(II)]-bis(Pi-hex-3-enedinitrile-Kappa 2N:N')] bis(tetrafluoridoborate)] | - |
dc.type | Article | - |
dc.identifier.doi | 10.1107/S2056989015009548 | - |
dc.identifier.scopusid | 2-s2.0-84983112924 | - |
dc.identifier.bibliographicCitation | Acta Crystallographica Section E: Crystallographic Communications, v.71, pp.m135 - m136 | - |
dc.description.isOpenAccess | TRUE | - |
dc.subject.keywordAuthor | crystal structure | - |
dc.subject.keywordAuthor | cobalt | - |
dc.subject.keywordAuthor | hex-3-enedinitrile | - |
dc.subject.keywordAuthor | hydrogen bonding | - |
dc.subject.keywordPlus | LITHIUM-ION BATTERIES | - |
dc.citation.endPage | m136 | - |
dc.citation.startPage | m135 | - |
dc.citation.title | Acta Crystallographica Section E: Crystallographic Communications | - |
dc.citation.volume | 71 | - |
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