Mechanistic Insights in Oxidative Reactions of Biomimetic Cobalt-Dioxygen Intermediates
- Title
- Mechanistic Insights in Oxidative Reactions of Biomimetic Cobalt-Dioxygen Intermediates
- Alternative Title
- 생체모방 코발트-이산소 중간체들의 산화반응에서의 메커니즘적 이해
- Author(s)
- Yeongjin Son
- DGIST Authors
- Yeongjin Son ; Nak Cheon Jeong ; Jaeheung Cho
- Advisor
- 정낙천
- Co-Advisor(s)
- Jaeheung Cho
- Issued Date
- 2023
- Awarded Date
- 2023-08-01
- Type
- Thesis
- Description
- Metalloenzyme; Biomimetic chemistry; Cobalt-dioxygen intermediates; Aldehyde deformylation; Nitrile activation; Mechanism study
- Table Of Contents
-
Contents
Abstract i
General Introduction 1
Chapter 1. Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate 13
1.1. Abstract 13
1.2. Introduction 14
1.3. Results and Discussion 17
1.4. Conclusion 69
1.5. Experimental Section 70
1.6. References 78
Chapter 2. Mechanistic Insights into Nitrile Activation by Cobalt(III)-Hydroperoxo Intermediates: The Influence of Ligand Basicity 85
2.1. Abstract 85
2.2. Introduction 87
2.3. Results and Discussion 90
2.4. Conclusion 127
2.5. Experimental Section 128
2.6. References 136
Concluding Remarks 147
- URI
-
http://hdl.handle.net/20.500.11750/46413
http://dgist.dcollection.net/common/orgView/200000685582
- Degree
- Doctor
- Department
- Department of Physics and Chemistry
- Publisher
- DGIST
- Related Researcher
-
-
Jeong, Nak Cheon
- Research Interests Inorganic Chemistry; Metal-Organic Framework; Nanoporous Materials; Electron Transport;Ion Transport
-
- Files in This Item:
-
There are no files associated with this item.
- Appears in Collections:
- Department of Physics and Chemistry Theses Ph.D.
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.