Title

Mechanistic Insights in Oxidative Reactions of Biomimetic Cobalt-Dioxygen Intermediates

Alternative Title

생체모방 코발트-이산소 중간체들의 산화반응에서의 메커니즘적 이해

DGIST Authors

Yeongjin Son ; Nak Cheon Jeong ; Jaeheung Cho

Advisor

정낙천

Co-Advisor(s)

Jaeheung Cho

Issued Date

2023

Awarded Date

2023-08-01

Citation

Yeongjin Son. (2023). Mechanistic Insights in Oxidative Reactions of Biomimetic Cobalt-Dioxygen Intermediates. doi: 10.22677/THESIS.200000685582

Type

Thesis

Description

Metalloenzyme; Biomimetic chemistry; Cobalt-dioxygen intermediates; Aldehyde deformylation; Nitrile activation; Mechanism study

Table Of Contents

Contents

Abstract i

General Introduction 1

Chapter 1. Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate 13
1.1. Abstract 13
1.2. Introduction 14
1.3. Results and Discussion 17
1.4. Conclusion 69
1.5. Experimental Section 70
1.6. References 78

Chapter 2. Mechanistic Insights into Nitrile Activation by Cobalt(III)-Hydroperoxo Intermediates: The Influence of Ligand Basicity 85
2.1. Abstract 85
2.2. Introduction 87
2.3. Results and Discussion 90
2.4. Conclusion 127
2.5. Experimental Section 128
2.6. References 136

Concluding Remarks 147

URI

http://hdl.handle.net/20.500.11750/46413
http://dgist.dcollection.net/common/orgView/200000685582

DOI

10.22677/THESIS.200000685582

Degree

Doctor

Department

Department of Physics and Chemistry

Publisher

DGIST

Show Full Item Record