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Enhanced Open-Circuit Voltage in Colloidal Quantum Dot Photovoltaics via Reactivity-Controlled Solution-Phase Ligand Exchange
- Enhanced Open-Circuit Voltage in Colloidal Quantum Dot Photovoltaics via Reactivity-Controlled Solution-Phase Ligand Exchange
- Jo, Jea Woong; Kim, Younghoon; Choi, Jongmin; de Arquer, F. Pelayo García; Walters, Grant; Sun, Bin; Ouellette, Olivier; Kim, Junghwan; Proppe, Andrew H.; Quintero-Bermudez, Rafael; Fan, James; Xu, Jixian; Tan, Chih Shan; Voznyy, Oleksandr; Sargent, Edward H.
- DGIST Authors
- Kim, Younghoon; Choi, Jongmin
- Issue Date
- Advanced Materials, 29(43)
- Article Type
- Author Keywords
- colloidal quantum dots; open-circuit voltage; photovoltaics; poly-dispersity; solution-phase ligand exchange
- LIGHT-EMITTING-DIODES; SOLAR-CELLS; SOLIDS; NANOCRYSTALS; PASSIVATION; ARCHITECTURE; PERFORMANCE; ABSORPTION; DEFICIT; INKS
- The energy disorder that arises from colloidal quantum dot (CQD) polydispersity limits the open-circuit voltage (VOC) and efficiency of CQD photovoltaics. This energy broadening is significantly deteriorated today during CQD ligand exchange and film assembly. Here, a new solution-phase ligand exchange that, via judicious incorporation of reactivity-engineered additives, provides improved monodispersity in final CQD films is reported. It has been found that increasing the concentration of the less reactive species prevents CQD fusion and etching. As a result, CQD solar cells with a VOC of 0.7 V (vs 0.61 V for the control) for CQD films with exciton peak at 1.28 eV and a power conversion efficiency of 10.9% (vs 10.1% for the control) is achieved. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
- Wiley-VCH Verlag
- Related Researcher
Chemical & Energy Materials Engineering (CEME) Laboratory
Advanced Metal Oxides; Colloidal Quantum Dots; Perovskite-Quantum Dot Hybrid Nanomaterials; Photocatalytic Materials
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- Division of Energy Technology1. Journal Articles
Department of Energy Science and EngineeringChemical & Energy Materials Engineering (CEME) Laboratory1. Journal Articles
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