Studies on Development of Cu-Catalyzed Silyl Addition to Allenes
- Title
- Studies on Development of Cu-Catalyzed Silyl Addition to Allenes
- Author(s)
- Yurim Lee
- DGIST Authors
- Yurim Lee ; Byunghyuck Jung ; Sunggi Lee
- Advisor
- 정병혁
- Co-Advisor(s)
- Sunggi Lee
- Issued Date
- 2024
- Awarded Date
- 2024-02-01
- Type
- Thesis
- Description
- Silylation;Allene;PhMe2SiBpin;2-Silyl-1;3-butadienes;Allylsilanes
- Table Of Contents
-
ABSTRACT i
LIST OF CONTENTS ii
Ⅰ. INTRODUCTION
1.1 Backgrounds 1
1.2 Previous reports
1.2.1 Preparation of 2-silyl-1,3-butadienes 1
1.2.2 Preparation of allylsilanes 3
1.3 Our strategy 4
II. RESULT AND DISCUSSIONS
2.1 Optimization of reaction conditions
2.1.1 Preparation of 2-silyl-1,3-butadiene 5
2.1.2 Preparation of (Z)-allylsilane 8
2.2 Substrate scopes
2.2.1 2-Silyl-1,3-butadienes with 2° allenols 10
2.2.2 2-Silyl-1,3-butadienes with other allenols 12
2.2.3 (Z)-Allylsilanes with mono-substituted allenes 13
2.3 Reaction mechanisms
2.3.1 Proposed catalytic cycle of 2-silyl-1,3-butadienes formation 14
2.3.2 Proposed catalytic cycle of allylsilanes formation 15
2.4 Synthetic applications of 2-silyl-1,3-butadienes 16
III. CONCLUSION 17
IV. EXPERIMENTAL SECTION 18
REFERENCE 49
국문 요약문 52
- URI
-
http://hdl.handle.net/20.500.11750/48119
http://dgist.dcollection.net/common/orgView/200000724550
- Degree
- Master
- Department
- Department of Physics and Chemistry
- Publisher
- DGIST
- Related Researcher
-
-
Jung, Byunghyuck
- Research Interests Organic Synthesis; Organo-transition metal chemistry; Catalytic Asymmetric Synthesis; Synthetic Methodologies; Synthesis of Natural Products and Drugs
-
- Files in This Item:
-
There are no files associated with this item.
- Appears in Collections:
- Department of Physics and Chemistry Theses Master
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.