Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Jin, Kangwoo | - |
dc.contributor.author | Park, Nohyoon | - |
dc.contributor.author | Ahn, Yongdeok | - |
dc.contributor.author | Seo, Daeha | - |
dc.contributor.author | Moon, Dohyun | - |
dc.contributor.author | Sung, Jooyoung | - |
dc.contributor.author | Park, Jinhee | - |
dc.date.accessioned | 2024-03-04T09:40:17Z | - |
dc.date.available | 2024-03-04T09:40:17Z | - |
dc.date.created | 2024-02-22 | - |
dc.date.issued | 2024-02 | - |
dc.identifier.issn | 2040-3364 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/48149 | - |
dc.description.abstract | We have rationally designed a one-dimensional coordination polymer (1D CP), termed 1D-DGIST-18, that exhibits intrinsic structural flexibility. This 1D CP enables its expansion into a three-dimensional network through supramolecular interactions involving coordinated solvents and/or ligands. The strategic selection of solvents for solvent exchange, prior to drying, significantly influences the structures of 1D-DGIST-18 by removing certain coordinating solvents and modulating π-π stacking. Consequently, a hierarchical porosity emerges, ranging from micro- to meso- to macroporous structures, which is attributed to its inherent structural dynamics. Additionally, the formation of excimers endows 1D-DGIST-18, when immersed in acetone, with ‘turn-on’ fluorescence, as evidenced by fluorescence decay profiles. These structural transitions within 1D-DGIST-18 are further elucidated using single-crystal X-ray diffractometry. The insights from this study provide a foundation for the design of materials with structural dynamics and tunable properties. © 2024 The Royal Society of Chemistry. | - |
dc.language | English | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | Solvent-induced structural transformation in a one-dimensional coordination polymer | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/d4nr00265b | - |
dc.identifier.wosid | 001159779600001 | - |
dc.identifier.scopusid | 2-s2.0-85185170824 | - |
dc.identifier.bibliographicCitation | Nanoscale, v.16, no.9, pp.4571 - 4577 | - |
dc.description.isOpenAccess | FALSE | - |
dc.subject.keywordPlus | PI STACKING | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | CRYSTAL | - |
dc.citation.endPage | 4577 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 4571 | - |
dc.citation.title | Nanoscale | - |
dc.citation.volume | 16 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied | - |
dc.type.docType | Article | - |
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