Department of Physics and Chemistry
Asymmetric Organic Synthesis and Drug Synthesis Laboratory
1. Journal Articles
Synthesis of secondary and tertiary amine-containing MOFs: C-N bond cleavage during MOF synthesis
- Title
- Synthesis of secondary and tertiary amine-containing MOFs: C-N bond cleavage during MOF synthesis
- Author(s)
- Hahm, Hyungwoo ; Ha, Hyeonbin ; Kim, Seongmin ; Jung, Byunghyuck ; Park, Myung Hwan ; Kim, Youngjo ; Heo, Jungseok ; Kim, Min
- Issued Date
- 2015-08
- Citation
- CrystEngComm, v.17, no.30, pp.5644 - 5650
- Type
- Article
- Keywords
- METAL-ORGANIC FRAMEWORK ; ALKYLATION ; OXIDATION ; SULFONAMIDES ; DEALKYLATION ; SERIES ; ACIDS
- ISSN
- 1466-8033
- Abstract
-
Secondary and tertiary amine-containing metal-organic frameworks (MOFs) have been synthesized, and unprecedented C-N bond cleavage phenomena were observed during MOF formation. Utilizing the secondary amine-containing ligand (BDC-NHMe), three new MOFs have been prepared, two of which are zinc(ii)-based, IRMOF-NHMe (IRMOF = isoreticular MOF) and DMOF-1-NHMe (DMOF = dabco MOF), in addition to the zirconium(iv)-based UiO-66-NHMe (UiO = University of Oslo). The tertiary amine-containing ligand (BDC-NMe
2 ) was converted to the secondary amine-containing ligand (BDC-NHMe) under both IRMOF and UiO-66 synthesis conditions, indicating an in situ C-N bond cleavage of ligand during MOF formation. In contrast, the tertiary amine-containing DMOF-1-NMe2 was successfully synthesized and studied for CO2 adsorption experiments. © The Royal Society of Chemistry 2015.
- Publisher
- Royal Society of Chemistry
- Related Researcher
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Jung, Byunghyuck
- Research Interests Organic Synthesis; Organo-transition metal chemistry; Catalytic Asymmetric Synthesis; Synthetic Methodologies; Synthesis of Natural Products and Drugs
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