Unlocking zinc storage in silver vanadate structures for high-performance aqueous zinc batteries

Abstract

Zinc-ion batteries (ZIBs) are being increasingly recognized as promising candidates for large-scale energy-storage systems owing to their stability in air, abundance of elemental zinc, low cost, and ease of handling. Although various cathode materials have been explored for ZIBs, silver vanadate stands out for its highly stable structure. However, the presence of silver in silver vanadate may hinder its electrochemical performance, necessitating activation over several cycles. In this study, we introduce an ion-exchange reaction to directly activate silver vanadate. The resulting ion-exchanged zinc vanadate demonstrates superior performance compared with silver vanadate, showcasing stable cycling behavior and high-rate capability. Remarkably, it maintains a capacity retention of 71 % even after 400 cycles. Analysis of the zinc intercalation mechanism reveals a combination of capacitive and diffusion-based processes contributing to energy storage in ZIBs. Post-cycling examinations reveal the presence of dendritic zinc anodes and confirm the stability and safety of the framework, with no silver migration to the anode side. These findings highlight the potential of ZIBs as next-generation energy-storage solutions and underscore the need for continued research in optimizing electrode materials and electrolytes for practical applications. © 2024 Elsevier B.V.