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Strong Coordination at Open-Metal Sites Enhances Hydrolytic Stability of Metal-Organic Frameworks
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Title
Strong Coordination at Open-Metal Sites Enhances Hydrolytic Stability of Metal-Organic Frameworks
Alternative Title
열린 금속 자리의 강한 배위결합을 통한 금속유기구조체의 수분안정성 향상
DGIST Authors
최재혁Nak Cheon JeongSeong Kyun Kim
Advisor
정낙천
Co-Advisor(s)
Seong Kyun Kim
Issued Date
2025
Awarded Date
2025-02-01
Citation
Jaehyeuk Choi. (2025). Strong Coordination at Open-Metal Sites Enhances Hydrolytic Stability of Metal-Organic Frameworks. doi: 10.22677/THESIS.200000843635
Type
Thesis
Description
Metal-Organic Frameworks, Open-Metal-Sites, Strong coordination, XRD, NMR
Table Of Contents
I. INTRODUCTION 1
II. EXPERIMENTAL METHODS & MATERIALS 3
III. RESULTS & DISCUSSION 5
3.1. HK structural features and hypothesis 5
3.1.1. Sample preparation and bonding strength 7
3.1.2. PXRD change and definition of calibrated retention ratio 9
3.1.3. Hydrolytic Stability and Confirmation of Metal-Linker Connectivity 11
3.2. Maintaining crystallinity of MOF due to connectivity of metal and organic ligands 13
3.2.1. Maintaining crystallinity of MOF due to connectivity of metal and organic ligands 15
3.2.2. Structure of HK and the reason for stability up to a coordination ratio of 0.3 16
IV. CONCLUSIONS 18
V. REFERENCES 19
URI
http://hdl.handle.net/20.500.11750/58069
http://dgist.dcollection.net/common/orgView/200000843635
DOI
10.22677/THESIS.200000843635
Degree
Master
Department
Department of Physics and Chemistry
Publisher
DGIST
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