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Regioselective Transformations of Unsaturated Systems Catalyzed by Low-Valent Nickel: Cycloaddition, Hydrosilylation, and Dicarbofunctionalization
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dc.contributor.author Kim, Gun Ha -
dc.contributor.author Jeon, Ji Hwan -
dc.contributor.author Jung, Byunghyuck -
dc.contributor.author Rohde, Jan-Uwe -
dc.contributor.author Hong, Sung You -
dc.date.accessioned 2025-07-03T09:40:09Z -
dc.date.available 2025-07-03T09:40:09Z -
dc.date.created 2025-06-30 -
dc.date.issued 2025-08 -
dc.identifier.issn 0936-5214 -
dc.identifier.uri https://scholar.dgist.ac.kr/handle/20.500.11750/58586 -
dc.description.abstract In this Account, we describe our recent research progress in the development of the functionalization of unsaturated substrates catalyzed by low-valent nickel. In particular, we discuss nickel-catalyzed azide–alkyne cycloaddition (NiAAC), [2 + 2 + 2] cycloaddition of diynes and nitriles, hydrosilylation of alkynes, and dicarbofunctionalization of 1,3-enynes. Moreover, we highlight our mechanistic studies aimed at elucidating catalytically active nickel intermediates, thereby contributing to the understanding and expansion of nickel-catalyzed synthetic methodologies. © 2025. Thieme. All rights reserved. -
dc.language English -
dc.publisher Thieme -
dc.title Regioselective Transformations of Unsaturated Systems Catalyzed by Low-Valent Nickel: Cycloaddition, Hydrosilylation, and Dicarbofunctionalization -
dc.type Article -
dc.identifier.doi 10.1055/a-2591-9299 -
dc.identifier.wosid 001510036700001 -
dc.identifier.scopusid 2-s2.0-105008706762 -
dc.identifier.bibliographicCitation Synlett, v.36, no.13, pp.1889 - 1899 -
dc.description.isOpenAccess FALSE -
dc.subject.keywordAuthor cycloaddition -
dc.subject.keywordAuthor unsaturated systems -
dc.subject.keywordAuthor hydrosilylation -
dc.subject.keywordAuthor dicarbofunctionalization -
dc.subject.keywordAuthor regioselectivity -
dc.subject.keywordAuthor reaction mechanisms -
dc.subject.keywordAuthor nickel -
dc.subject.keywordPlus COUPLING REACTIONS -
dc.subject.keywordPlus TERMINAL ALKYNES -
dc.subject.keywordPlus C-C -
dc.subject.keywordPlus AIR -
dc.subject.keywordPlus 1,4-ALKYLARYLATION -
dc.subject.keywordPlus 1,3-ENYNES -
dc.subject.keywordPlus REACTIVITY -
dc.subject.keywordPlus COMPLEXES -
dc.subject.keywordPlus PALLADIUM -
dc.subject.keywordPlus AZIDE-ALKYNE CYCLOADDITION -
dc.citation.endPage 1899 -
dc.citation.number 13 -
dc.citation.startPage 1889 -
dc.citation.title Synlett -
dc.citation.volume 36 -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.relation.journalResearchArea Chemistry -
dc.relation.journalWebOfScienceCategory Chemistry, Organic -
dc.type.docType Article -
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정병혁
Jung, Byunghyuck정병혁

Department of Physics and Chemistry

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