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Defect Engineering into Metal-Organic Frameworks for the Rapid and Sequential Installation of Functionalities

Title
Defect Engineering into Metal-Organic Frameworks for the Rapid and Sequential Installation of Functionalities
Authors
Park, Hyo JinKim, Seong WooJung, ByunghyuckPark, Myung HwanKim, Young JoKim, Min
DGIST Authors
Jung, Byunghyuck
Issue Date
2018-02
Citation
Inorganic Chemistry, 57(3), 1040-1047
Type
Article
Article Type
Article
ISSN
0020-1669
Abstract
Postsynthetic treatments are well-known and important functionalization tools of metal-organic frameworks (MOFs). Herein, we have developed a practical and rapid postsynthetic ligand exchange (PSE) strategy using a defect-controlled MOF. An increase in the number of defects amounts to MOFs with enhanced rates of ligand exchange in a shorter time frame. An almost quantitative exchange was achieved by using the most defective MOFs. This PSE strategy is a straightforward method to introduce a functionality into MOFs including bulky or catalytically relevant moieties. Furthermore, some mechanistic insights into PSE were revealed, allowing for a sequential ligand exchange and the development of multifunctional MOFs with controlled ligand ratios. © 2018 American Chemical Society.
URI
http://hdl.handle.net/20.500.11750/5918
DOI
10.1021/acs.inorgchem.7b02391
Publisher
American Chemical Society
Related Researcher
  • Author Jung, Byunghyuck Asymmetric Organic Synthesis and Drug Synthesis Laboratory
  • Research Interests Organic Synthesis; Organo-transition metal chemistry; Catalytic Asymmetric Synthesis; Synthetic Methodologies; Synthesis of Natural Products and Drugs
Files:
There are no files associated with this item.
Collection:
School of Undergraduate Studies1. Journal Articles


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