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Ionic Conductivity Enhancement through Structural Disorder in Solid Electrolytes

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Title
Ionic Conductivity Enhancement through Structural Disorder in Solid Electrolytes
Alternative Title
구조적 무질서 유도를 통한 이온 전도도 향상
DGIST Authors
InKyoung HanSeung-Tae HongHochun Lee
Advisor
홍승태
Co-Advisor(s)
Hochun Lee
Issued Date
2026
Awarded Date
2026-02-01
Type
Thesis
Description
Solid Electrolyte
Table Of Contents
Ⅰ. Introduction 1
1.1 The Necessity of Research on All-Solid-State Batteries 1
1.2 Role of Structural Design in Solid Electrolytes 3
1.3 Introduction to Li2ZnCl4 4
1.4 Introduction to Li5AlS4 5

Ⅱ. Experimental 7
2.1 Synthesis 7
2.1.1 Synthesis of Li2ZnCl4 7
2.1.2 Synthesis of Li5AlS4 7
2.2 Materials characterization 10
2.2.1 Structure Analysis and Design Strategy for Li2ZnCl4 10
2.2.2 Electrochemical Evaluation of Li2ZnCl4 11
2.2.3 Structure Analysis and Design Strategy for Li5AlS4 12
2.2.4 Electrochemical Evaluation of Li5AlS4 13

Ⅲ. Results and discussions 14
3.1 Results of Li2ZnCl4 14
3.1.1 Structure Properties 14
3.1.2 Li+ ions Transport Properties 22
3.2 Results of Li5AlS4 25
3.2.1 Structure Properties 25
3.2.2 Electrochemical performance 35

Ⅳ. Conclusion 37

Ⅴ. References 39
URI
https://scholar.dgist.ac.kr/handle/20.500.11750/59695
http://dgist.dcollection.net/common/orgView/200000942628
DOI
10.22677/THESIS.200000942628
Degree
Master
Department
Department of Energy Science and Engineering
Publisher
DGIST
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