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Composition–Function Relationship in Nominally Porous Metal–Organic Frameworks

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Title
Composition–Function Relationship in Nominally Porous Metal–Organic Frameworks
Alternative Title
구조적 다공성 금속–유기 구조체에서의 조성–기능 상관관계
DGIST Authors
Eunho SeoJinhee Park
Advisor
박진희
Issued Date
2026
Awarded Date
2026-02-01
Type
Thesis
Description
Metal–organic frameworks, Mixed metal MOFs, Adsorbent, Photothermal conversion, Catalyst
Table Of Contents
List of Contents
Abstract i
List of contents ii
List of tables iv
List of figures v
List of schemes vii

Ⅰ. Introduction 1
Ⅱ. Experimental Methods 4
2.1 Materials 4
2.2 Measurements 5
2.3 Syntheses 6
2.3.1 Synthesis of Ti6O6(OiPr)6(AB)6 6
2.3.2 Synthesis of Ti6O6(OiPr)6(t-BA)6 6
2.3.3 Synthesis of N,N'-bis(3-hydroxybenzoic acid)-1,4,5,8-naphthalenediimide (H2L) 7
2.3.4 Syntheses of M-DGIST-20 7
2.4 Post-synthetic imidazole incorporation 10
2.5 Iodine adsorption measurements 11
2.6 Photoactivity test 12
2.7 Photothermal conversion experiments 13
2.8 Catalytic activity test 13
Ⅲ. Results and Discussions 14
3.1 Synthesis and characterization of DGIST-20 14
3.2 Iodine adsorption 22
3.3 Photoactivity 26
3.4 Photothermal conversion 28
3.5 Photothermal-assisted catalysis 30
Ⅳ. Conclusions 33
Ⅴ. References 34
Ⅵ. Summary 38
URI
https://scholar.dgist.ac.kr/handle/20.500.11750/59742
http://dgist.dcollection.net/common/orgView/200000943575
DOI
10.22677/THESIS.200000943575
Degree
Master
Department
Department of Physics and Chemistry
Publisher
DGIST
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