Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Peralta, Ricardo A. | - |
dc.contributor.author | Lyu, P. | - |
dc.contributor.author | López-Olvera, A. | - |
dc.contributor.author | Obeso, J.L. | - |
dc.contributor.author | Leyva, C. | - |
dc.contributor.author | Jeong, Nak Cheon | - |
dc.contributor.author | Ibarra, I.A. | - |
dc.contributor.author | Maurin, G. | - |
dc.date.accessioned | 2022-11-14T16:40:11Z | - |
dc.date.available | 2022-11-14T16:40:11Z | - |
dc.date.created | 2022-11-05 | - |
dc.date.issued | 2022-11 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/17112 | - |
dc.description.abstract | Uncommon reversible guest-induced metal-hemilabile linker bond dynamics in MOF MFM-300(Sc) was unraveled to switch on/switch off catalytic open metal sites. The catalytic activity of this MOF with non-permanent open metal sites was demonstrated using a model Strecker hydrocyanation reaction as a proof-of-concept. Conclusively, the catalytic activity was evidenced to be fully reversible, preserving the conversion performance and structure integrity of MFM-300(Sc) over multiple cycles. These experimental findings were corroborated by quantum-calculations that revealed a reaction mechanism driven by the Sc-open metal sites. This discovery paves the way towards the design of new effective and easily regenerable heterogeneous MOF catalysts integrating switchable metal sites. © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. | - |
dc.language | English | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | Switchable Metal Sites in Metal–Organic Framework MFM-300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.202210857 | - |
dc.identifier.wosid | 000871723000001 | - |
dc.identifier.scopusid | 2-s2.0-85140390179 | - |
dc.identifier.bibliographicCitation | Angewandte Chemie - International Edition, v.61, no.48 | - |
dc.description.isOpenAccess | TRUE | - |
dc.subject.keywordAuthor | Catalysis | - |
dc.subject.keywordAuthor | Density Functional Theory | - |
dc.subject.keywordAuthor | Metal-Hemilabile Linker Bond Dynamics | - |
dc.subject.keywordAuthor | MOFs | - |
dc.subject.keywordAuthor | Reaction Mechanism | - |
dc.subject.keywordPlus | STRECKER REACTION | - |
dc.subject.keywordPlus | BRONSTED ACIDITY | - |
dc.subject.keywordPlus | COORDINATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | TRIFLATE | - |
dc.subject.keywordPlus | WATER | - |
dc.citation.number | 48 | - |
dc.citation.title | Angewandte Chemie - International Edition | - |
dc.citation.volume | 61 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.type.docType | Article | - |
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