Meta-Selective C-H Functionalization of Arylsilanes Using a Silicon Tethered Directing Group
- Title
- Meta-Selective C-H Functionalization of Arylsilanes Using a Silicon Tethered Directing Group
- Author(s)
- Bang, Jaehan ; Gi, Seyun ; Lee, Yoonjung ; Tan, Kian L. ; Lee, Sunggi
- Issued Date
- 2022-07
- Citation
- Organic Letters, v.24, no.28, pp.5181 - 5185
- Type
- Article
- Keywords
- LEWIS-ACID ; ACTIVATION ; OLEFINATION ; TEMPLATE ; BONDS ; ARENES ; SILYLATION ; TRACELESS ; MECHANISM ; ARYLATION
- ISSN
- 1523-7060
- Abstract
- We describe meta-selective C-H functionalization of arylsilanes using a Si-tethered directing group. The current method enables a selective alkenylation of arenes bearing a variety of functional groups, and several electron-deficient olefins are also applicable as coupling partners. Further functional group transformations of the silicon-tethered directing group provide multi substituted arenes efficiently.
- Publisher
- American Chemical Society
- Related Researcher
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Lee, Sunggi
- Research Interests Organic synthesis; Catalyst development; Reaction development; Radical chemistry; Stereoselective reaction
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- Appears in Collections:
- Department of Physics and Chemistry Organic Synthesis & Catalysis Lab 1. Journal Articles
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