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dc.contributor.author Jung, Yongju -
dc.contributor.author Kim, Seok -
dc.contributor.author Spray, Ryan L. -
dc.contributor.author Yang, Hye Jeong -
dc.contributor.author Park, Seong-Hyo -
dc.contributor.author Kim, Seokhyeon -
dc.contributor.author Lee, Hochun -
dc.date.available 2017-07-11T05:42:37Z -
dc.date.created 2017-04-18 -
dc.date.issued 2015-12 -
dc.identifier.issn 0253-2964 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/2801 -
dc.description.abstract Nanometer-scale (approximately 70 nm) silica/polypyrrole composites were synthesized using a selective polymerization based on an in situ-generated strong oxidizing agent (NO+ ions) on the silica surface. The effects of the concentrations of reactants (pyrrole monomer and NO2- ions) and the presence of additional dopant anions (Cl- or SO2-4) on the polypyrrole (ppy) content and electric conductivity of the silica/ppy composites are examined. It was found that the ppy content in the silica/ppy composites increased with the reactant concentration in the range of 0.02-0.2 M. It is revealed that employing additional dopant anions could be a promising way to improve the electrical conductivity of the composites. © 2015 Korean Chemical Society, Seoul & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. -
dc.publisher Wiley-VCH Verlag -
dc.title Effects of Selective Polymerization Conditions on Physical Properties of Nanometer-Scale Silica/Polypyrrole Composites -
dc.type Article -
dc.identifier.doi 10.1002/bkcs.10589 -
dc.identifier.scopusid 2-s2.0-84954314250 -
dc.identifier.bibliographicCitation Bulletin of the Korean Chemical Society, v.36, no.12, pp.2881 - 2884 -
dc.identifier.kciid ART002055924 -
dc.description.isOpenAccess FALSE -
dc.subject.keywordAuthor Electrical conductivity -
dc.subject.keywordAuthor Polypyrrole -
dc.subject.keywordAuthor Selective polymerization -
dc.subject.keywordAuthor Silica -
dc.subject.keywordPlus Electric Conductivity -
dc.subject.keywordPlus Electrical Conductivity -
dc.subject.keywordPlus Ions -
dc.subject.keywordPlus Nano-Meter Scale -
dc.subject.keywordPlus Nanocomposites -
dc.subject.keywordPlus NANOPARTICLES -
dc.subject.keywordPlus Oxidizing Agents -
dc.subject.keywordPlus PARTICLES -
dc.subject.keywordPlus Polymerization -
dc.subject.keywordPlus Polypyrrole -
dc.subject.keywordPlus Polypyrrole (PPy) -
dc.subject.keywordPlus Polypyrroles -
dc.subject.keywordPlus Pyrrole Monomers -
dc.subject.keywordPlus Reactant Concentrations -
dc.subject.keywordPlus Selective Polymerization -
dc.subject.keywordPlus Selective Polymerizations -
dc.subject.keywordPlus Silica -
dc.subject.keywordPlus Silica Surface -
dc.subject.keywordPlus SPHERES -
dc.subject.keywordPlus SURFACE -
dc.citation.endPage 2884 -
dc.citation.number 12 -
dc.citation.startPage 2881 -
dc.citation.title Bulletin of the Korean Chemical Society -
dc.citation.volume 36 -
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Department of Energy Science and Engineering Electrochemistry Laboratory for Sustainable Energy(ELSE) 1. Journal Articles

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