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Hybrid CuxO-TiO2 Heterostructured Composites for Photocatalytic CO2 Reduction into Methane Using Solar Irradiation: Sunlight into Fuel
- Hybrid CuxO-TiO2 Heterostructured Composites for Photocatalytic CO2 Reduction into Methane Using Solar Irradiation: Sunlight into Fuel
- Park, Seung Min; Razzaq, Abdul; Park, Young Ho; Sorcar, Saurav; Park, Yi Seul; Grimes, C. A.; In, Su Il
- DGIST Authors
- In, Su Il
- Issue Date
- ACS Omega, 1(5), 868-875
- Article Type
- Photocatalytic CO2 conversion to fuel offers an exciting prospect for solar energy storage and transportation thereof. Several photocatalysts have been employed for CO2 photoreduction; the challenge of realizing a low-cost, readily synthesized photocorrosion-stable photocatalytic material that absorbs and successfully utilizes a broad portion of the solar spectrum energy is as yet unmet. Herein, a mesoporous p-type/n-type heterojunction material, CuxO-TiO2 (x = 1, 2), is synthesized via annealing of Cu/Cu2O nanocomposites mixed with a TiO2 precursor (TiCl4). Such an experimental approach in which two materials of diverse bandgaps are coupled provides a simultaneous opportunity for greater light absorption and rapid charge separation because of the intrinsic p-n heterojunction nature of the material. As detailed herein, this heterostructured photocatalyst demonstrates an improved photocatalytic activity. With the CO2 reduction of our optimal sample (augmented light absorption, efficacious charge separation, and mesoporosity) that utilizes no metal cocatalysts, a remarkable methane yield of 221.63 ppm·g-1·h-1 is achieved. © 2016 American Chemical Society.
- American Chemical Society
- Related Researcher
Green and Renewable Energy for Endless Nature(GREEN) Lab
CO2 conversion to hydrocarbon fuels; Water splitting for hydrogen generation; Quantum dot devices; Dye sensitized solar cells; Environmental remediation; Synthesis of functional nanomaterials; CO2 연료전환; 수소생산을 위한 광전기화학적 물분해; 양자점 태양전지; 염료감응 태양전지; 공해물질 저감연구; 기능성 나노소재 개발
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- Department of Energy Science and EngineeringGreen and Renewable Energy for Endless Nature(GREEN) Lab1. Journal Articles
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