Title

Earth-Abundant Transition Metal-Catalyzed Regioselective Hydrosilylation of Allenes

DGIST Authors

Seongha Kim ; Byunghyuck Jung ; Sangwon Seo

Advisor

정병혁

Co-Advisor(s)

Sangwon Seo

Issued Date

2025

Awarded Date

2025-08-01

Type

Thesis

Description

Allene, Protosilylation, Hydrosilylation, Allylsilanes, Cu-catalyst, Ni-catalyst, On-water

Table Of Contents

ABSTRACT i
LIST OF CONTENTS ii

Ⅰ. INTRODUCTION 1
1.1 Backgrounds and previous studies 1
1.2 Our works 1
ⅠⅠ. RESULTS AND DISCUSSIONS 2
2.1 Cu-catalyzed protosilyaltion of allenes. 2
2.1.1 Reaction Optimization 2
2.1.1.1 Optimization for protosilylation of mono-substituted allene 2
2.1.1.2 Optimization for protosilylation under on-water conditions 7
2.1.2 Substrate Scopes 8
2.1.2.1 Substrate scopes for protosilylation of mono-substituted allene 8
2.1.2.2 Substrate scopes for protosilylation under on-water conditions 9
2.1.3 Mechanistic Studies 10
2.1.4 Synthetic application 13
2.2 Ni-catalyzed hydrosilyaltion of allenes. 14
2.2.1 Reaction Optimization 14
2.2.2 Substrate Scopes 17
2.2.3 Mechanistic Studies 18
III. CONCLUSION 21
IV. EXPERIMENTAL SECTION 22
REFERENCE 57
국문 요약문 61

URI

https://scholar.dgist.ac.kr/handle/20.500.11750/59848
http://dgist.dcollection.net/common/orgView/200000889871

DOI

10.22677/THESIS.200000889871

Degree

Master

Department

Department of Physics and Chemistry

Publisher

DGIST

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