Title

In Situ Synthesis of Metalloporphyrin Metal–Organic Frameworks via Porphyrinic Core Activation

Alternative Title

포르피린 중심부 활성화를 통한 금속포르피린 형성과 금속-유기 구조체의 동시 합성

DGIST Authors

Sujeong Yu ; Jinhee Park

Advisor

박진희

Issued Date

2026

Awarded Date

2026-08-01

Type

Thesis

Description

Metal–organic frameworks, Metalloporphyrin MOFs, In situ metalation, Porphyrin core metalation

Table Of Contents

List of Contents
Abstract i
List of contents ⅱ
List of figures ⅳ
List of schemes ⅵi

I. Introduction 1
II. Experimental Methods
2.1 Materials 5
2.2 Measurements 6
2.3 Syntheses 6
2.3.1 Synthesis of TCPP 6
2.3.2 Synthesis of CoCa-TCPP-I 9
2.3.3 Synthesis of CoCa-TCPP-II 9
2.3.4 Synthesis of Fe-TCPP-I 9
2.3.5 Synthesis of Fe-TCPP-II 9
III. Results and Discussions
3.1 Co–Ca Metalloporphyrin Frameworks 10
3.1.1 Synthesis and crystal structure of CoCa-TCPP-I 10
3.1.2 Synthesis and crystal structure of CoCa-TCPP-II 17
3.1.3 Solvent stability test of Co–Ca Metalloporphyrin Frameworks 19
3.1.4 Comparison of CoCa-TCPP-I and CoCa-TCPP-II 21
3.2 Iron-Based Metalloporphyrin Frameworks 23
3.2.1 Design and Crystal Structure of Fe-TCPP-I 23
3.2.2 Exfoliation Strategy and Morphological Impact 25
3.2.3 Synthesis and Exfoliation of Fe-TCPP-II 28
3.2.4 Structural Characterization of Fe-TCPP Frameworks 32
3.2.5 Water stability test of Fe-TCPP 34
3.2.6 Catalytic activity 37
Ⅳ. References 40
Ⅴ. Summary 45

URI

https://scholar.dgist.ac.kr/handle/20.500.11750/60830
http://dgist.dcollection.net/common/orgView/200001014839

DOI

10.22677/THESIS.200001014839

Degree

Master

Department

Department of Physics and Chemistry

Publisher

DGIST

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