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dc.contributor.author Lee, Byeongchan -
dc.contributor.author Park, Jinhee -
dc.date.accessioned 2021-03-11T05:36:18Z -
dc.date.available 2021-03-11T05:36:18Z -
dc.date.created 2021-01-28 -
dc.date.issued 2021-02 -
dc.identifier.citation Bulletin of the Korean Chemical Society, v.42, no.2, pp.290 - 293 -
dc.identifier.issn 0253-2964 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/12987 -
dc.identifier.uri https://onlinelibrary.wiley.com/cms/asset/50c0f934-ab88-4552-b9fc-c3f839a88e2a/bkcs.v42.2.cover.jpg -
dc.description.abstract In this work, the effect of functional groups on I2 sorption kinetics is investigated using two different types of isostructural metal-organic frameworks, UiO-66-X series (X = H, Br, NO2, NH2, (OH)2, and (COOH)2) and M2(m-DOBDC) series, (M = Co2+, Mg2+, and Ni2+; m-DOBDC4− = 4,6-dioxo-1,3-benzenedicarboxylate). Among the UiO-66-X series, UiO-66-(COOH)2 exhibits the fastest sorption kinetics and the highest sorption capacity due to dipole-induced dipole interactions between carboxylic acid groups and I2 molecules. In addition, faster I2 chemisorption is observed in M2(m-DOBDC) because of electrophilic aromatic substitution of m-DOBDC4− with I2. The I2 sorption mechanisms are further supported by fitting the I2 adsorption kinetics data to pseudo-first-order and pseudo-second-order kinetic models. © 2021 Korean Chemical Society, Seoul & Wiley-VCH GmbH -
dc.language English -
dc.publisher Korean Chemical Society -
dc.title Effect of Functional Groups on the I2 Sorption Kinetics of Isostructural Metal–Organic Frameworks -
dc.type Article -
dc.identifier.doi 10.1002/bkcs.12201 -
dc.identifier.wosid 000608456100001 -
dc.identifier.scopusid 2-s2.0-85099480725 -
dc.type.local Article(Overseas) -
dc.type.rims ART -
dc.description.journalClass 1 -
dc.citation.publicationname Bulletin of the Korean Chemical Society -
dc.identifier.kciid ART002685076 -
dc.contributor.nonIdAuthor Lee, Byeongchan -
dc.identifier.citationVolume 42 -
dc.identifier.citationNumber 2 -
dc.identifier.citationStartPage 290 -
dc.identifier.citationEndPage 293 -
dc.identifier.citationTitle Bulletin of the Korean Chemical Society -
dc.type.journalArticle Article -
dc.description.isOpenAccess N -
dc.subject.keywordAuthor Metal-organic frameworks -
dc.subject.keywordAuthor Iodine capture -
dc.subject.keywordAuthor Functional group effects -
dc.subject.keywordAuthor Sorption kinetics -
dc.contributor.affiliatedAuthor Lee, Byeongchan -
dc.contributor.affiliatedAuthor Park, Jinhee -
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Department of Physics and Chemistry Organic-Inorganic Hybrids Lab 1. Journal Articles

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