Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Byeongchan | - |
dc.contributor.author | Park, Jinhee | - |
dc.date.accessioned | 2021-03-11T05:36:18Z | - |
dc.date.available | 2021-03-11T05:36:18Z | - |
dc.date.created | 2021-01-28 | - |
dc.date.issued | 2021-02 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/12987 | - |
dc.description.abstract | In this work, the effect of functional groups on I2 sorption kinetics is investigated using two different types of isostructural metal-organic frameworks, UiO-66-X series (X = H, Br, NO2, NH2, (OH)2, and (COOH)2) and M2(m-DOBDC) series, (M = Co2+, Mg2+, and Ni2+; m-DOBDC4− = 4,6-dioxo-1,3-benzenedicarboxylate). Among the UiO-66-X series, UiO-66-(COOH)2 exhibits the fastest sorption kinetics and the highest sorption capacity due to dipole-induced dipole interactions between carboxylic acid groups and I2 molecules. In addition, faster I2 chemisorption is observed in M2(m-DOBDC) because of electrophilic aromatic substitution of m-DOBDC4− with I2. The I2 sorption mechanisms are further supported by fitting the I2 adsorption kinetics data to pseudo-first-order and pseudo-second-order kinetic models. © 2021 Korean Chemical Society, Seoul & Wiley-VCH GmbH | - |
dc.language | English | - |
dc.publisher | Korean Chemical Society | - |
dc.title | Effect of Functional Groups on the I2 Sorption Kinetics of Isostructural Metal–Organic Frameworks | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/bkcs.12201 | - |
dc.identifier.wosid | 000608456100001 | - |
dc.identifier.scopusid | 2-s2.0-85099480725 | - |
dc.identifier.bibliographicCitation | Bulletin of the Korean Chemical Society, v.42, no.2, pp.290 - 293 | - |
dc.identifier.kciid | ART002685076 | - |
dc.description.isOpenAccess | FALSE | - |
dc.subject.keywordAuthor | Metal-organic frameworks | - |
dc.subject.keywordAuthor | Iodine capture | - |
dc.subject.keywordAuthor | Functional group effects | - |
dc.subject.keywordAuthor | Sorption kinetics | - |
dc.subject.keywordPlus | IODINE CAPTURE | - |
dc.subject.keywordPlus | ORDER | - |
dc.subject.keywordPlus | MOFS | - |
dc.identifier.url | https://onlinelibrary.wiley.com/cms/asset/50c0f934-ab88-4552-b9fc-c3f839a88e2a/bkcs.v42.2.cover.jpg | - |
dc.citation.endPage | 293 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 290 | - |
dc.citation.title | Bulletin of the Korean Chemical Society | - |
dc.citation.volume | 42 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.type.docType | Article | - |
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