Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Jeong, Yong Chan | - |
dc.contributor.author | Song, Sang Yong | - |
dc.contributor.author | Kim, Youngjae | - |
dc.contributor.author | Oh, Youngtek | - |
dc.contributor.author | Kang, Joongoo | - |
dc.contributor.author | Seo, Jungpil | - |
dc.date.available | 2017-07-05T08:47:53Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2015-12-10 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/2316 | - |
dc.description.abstract | Pinning single molecules at desired positions can provide opportunities to fabricate bottom-up designed molecular machines. Using the combined approach of scanning tunneling microscopy and density functional theory, we report on tip-induced anchoring of Ni-phthalocyanine molecules on an Au(111) substrate. We demonstrate that the tip-induced current leads to the dehydrogenation of a benzene-like ligand in the molecule, which subsequently creates chemical bonds between the molecule and the substrate. It is also found that the diffusivity of Ni-phthalocyanine molecules is dramatically reduced when the molecules are anchored on the Au adatoms produced by bias pulsing. The tip-induced molecular anchoring would be readily applicable to other functional molecules that contain similar ligands. © 2015 American Chemical Society. | - |
dc.publisher | American Chemical Society | - |
dc.title | Tip-Induced Molecule Anchoring in Ni Phthalocyanine on Au(111) Substrate | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.jpcc.5b05908 | - |
dc.identifier.scopusid | 2-s2.0-84949595691 | - |
dc.identifier.bibliographicCitation | Journal of Physical Chemistry C, v.119, no.49, pp.27721 - 27726 | - |
dc.subject.keywordPlus | Au (111) Substrates | - |
dc.subject.keywordPlus | AUGMENTED-WAVE METHOD | - |
dc.subject.keywordPlus | Bond Strength (Chemical) | - |
dc.subject.keywordPlus | Bottom Up | - |
dc.subject.keywordPlus | CHemICAL-REACTION | - |
dc.subject.keywordPlus | Density Functional Theory | - |
dc.subject.keywordPlus | Desired Position | - |
dc.subject.keywordPlus | Functional Molecules | - |
dc.subject.keywordPlus | Ligands | - |
dc.subject.keywordPlus | Molecular Machines | - |
dc.subject.keywordPlus | Molecules | - |
dc.subject.keywordPlus | Nickel | - |
dc.subject.keywordPlus | Nitrogen Compounds | - |
dc.subject.keywordPlus | Phthalocyanine Molecules | - |
dc.subject.keywordPlus | Scanning Tunneling Microscopy | - |
dc.subject.keywordPlus | SINGLE | - |
dc.subject.keywordPlus | Single Molecule | - |
dc.subject.keywordPlus | SURFACE | - |
dc.subject.keywordPlus | Tip-Induced | - |
dc.citation.endPage | 27726 | - |
dc.citation.number | 49 | - |
dc.citation.startPage | 27721 | - |
dc.citation.title | Journal of Physical Chemistry C | - |
dc.citation.volume | 119 | - |
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