Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Park, H. | - |
dc.contributor.author | Yoo, K. | - |
dc.contributor.author | Jung, Byung Hyuck | - |
dc.contributor.author | Kim, M. | - |
dc.date.accessioned | 2018-04-11T03:46:12Z | - |
dc.date.available | 2018-04-11T03:46:12Z | - |
dc.date.created | 2018-03-29 | - |
dc.date.issued | 2018-04 | - |
dc.identifier.issn | 0040-4020 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/6142 | - |
dc.description.abstract | The first direct synthesis of substituted anthracenes from o-tolualdehydes and aryl iodides via a Pd(II)-catalyzed C. H arylation using an alcohol-bearing transient directing group and subsequent AgOTf-assisted electrophilic aromatic cyclization is described. New transient directing groups consisting of amino acids and amino alcohols enhanced the reactivity, and the C. H arylation was complete in 12 h at 90 °C. By simply changing the silver salt to silver triflate, the one-pot synthesis of anthracene derivatives was carried out using the present reaction conditions. © 2018 Elsevier Ltd. | - |
dc.language | English | - |
dc.publisher | Elsevier Ltd | - |
dc.title | Direct synthesis of anthracenes from o-tolualdehydes and aryl iodides through Pd(II)-Catalyzed sp3 CH arylation and electrophilic aromatic cyclization | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.tet.2018.03.006 | - |
dc.identifier.scopusid | 2-s2.0-85043281525 | - |
dc.identifier.bibliographicCitation | Tetrahedron, v.74, no.16, pp.2048 - 2055 | - |
dc.description.isOpenAccess | FALSE | - |
dc.subject.keywordAuthor | Transient directing groups | - |
dc.subject.keywordAuthor | C-H activation | - |
dc.subject.keywordAuthor | sp(3) C-H arylation | - |
dc.subject.keywordAuthor | One-pot synthesis | - |
dc.subject.keywordAuthor | Anthracenes | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORK | - |
dc.subject.keywordPlus | BOND ACTIVATION | - |
dc.subject.keywordPlus | ATOM ECONOMY | - |
dc.subject.keywordPlus | C(SP(3))-H ARYLATION | - |
dc.subject.keywordPlus | ALIPHATIC-KETONES | - |
dc.subject.keywordPlus | NATURAL-PRODUCTS | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | CONSTRUCTION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.citation.endPage | 2055 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 2048 | - |
dc.citation.title | Tetrahedron | - |
dc.citation.volume | 74 | - |
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