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dc.contributor.author Keum, Yesub -
dc.contributor.author Park, Seonghun -
dc.contributor.author Chen, Ying-Pin -
dc.contributor.author Park, Jinhee -
dc.date.accessioned 2018-10-30T05:59:14Z -
dc.date.available 2018-10-30T05:59:14Z -
dc.date.created 2018-10-30 -
dc.date.issued 2018-11 -
dc.identifier.citation Angewandte Chemie - International Edition, v.57, no.45, pp.14852 - 14856 -
dc.identifier.issn 1433-7851 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/9362 -
dc.description.abstract Titanium(IV)-based metal-organic frameworks (Ti-MOFs) have received significant attention in recent years due to their numerous photocatalytic applications. We herein prepare the single-crystalline Ti-carboxylate MOF (DGIST-1) composed of an unprecedented Ti-oxo chain cluster and the porphyrinic ligand, TCPP (tetrakis(4-carboxyphenyl)porphyrin). Preformed Ti-oxo clusters were used as Ti4+ sources to avoid the spontaneous hydrolysis and condensation reactions of traditional Ti-alkoxide precursors, thus, enabling the formation of the highly crystalline Ti-MOF. The successfully activated DGIST-1 exhibited a higher surface area (i.e., 1957.3 m2 g−1) than previously reported Ti-MOFs due to its high crystallinity. Furthermore, the visible-light-responsive photocatalytic activity of DGIST-1 was confirmed by the simultaneous generation of singlet oxygen (1O2) and superoxide (.O2 −) species, in addition to the highly efficient and selective oxidation of benzyl alcohol to benzaldehyde. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim -
dc.language English -
dc.publisher John Wiley & Sons Ltd. -
dc.title Titanium-Carboxylate Metal-Organic Framework Based on an Unprecedented Ti-Oxo Chain Cluster -
dc.type Article -
dc.identifier.doi 10.1002/anie.201809762 -
dc.identifier.wosid 000452234400029 -
dc.identifier.scopusid 2-s2.0-85054740968 -
dc.type.local Article(Overseas) -
dc.type.rims ART -
dc.description.journalClass 1 -
dc.citation.publicationname Angewandte Chemie - International Edition -
dc.contributor.nonIdAuthor Keum, Yesub -
dc.contributor.nonIdAuthor Park, Seonghun -
dc.contributor.nonIdAuthor Chen, Ying-Pin -
dc.identifier.citationVolume 57 -
dc.identifier.citationNumber 45 -
dc.identifier.citationStartPage 14852 -
dc.identifier.citationEndPage 14856 -
dc.identifier.citationTitle Angewandte Chemie - International Edition -
dc.type.journalArticle Article -
dc.description.isOpenAccess N -
dc.subject.keywordAuthor cluster compounds -
dc.subject.keywordAuthor metal-organic frameworks -
dc.subject.keywordAuthor reactive oxygen species -
dc.subject.keywordAuthor selective alcohol oxidation -
dc.subject.keywordAuthor Ti-oxo chain cluster -
dc.subject.keywordPlus SINGLET OXYGEN -
dc.subject.keywordPlus CO2 REDUCTION -
dc.subject.keywordPlus PHOTOCATALYSIS -
dc.subject.keywordPlus WATER -
dc.subject.keywordPlus MECHANISMS -
dc.subject.keywordPlus CHEMISTRY -
dc.subject.keywordPlus REACTIVITY -
dc.subject.keywordPlus COMPLEXES -
dc.subject.keywordPlus MOF -
dc.contributor.affiliatedAuthor Keum, Yesub -
dc.contributor.affiliatedAuthor Park, Seonghun -
dc.contributor.affiliatedAuthor Chen, Ying-Pin -
dc.contributor.affiliatedAuthor Park, Jinhee -
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Department of Physics and Chemistry Organic-Inorganic Hybrids Lab 1. Journal Articles

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