Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Keum, Yesub | - |
dc.contributor.author | Park, Seonghun | - |
dc.contributor.author | Chen, Ying-Pin | - |
dc.contributor.author | Park, Jinhee | - |
dc.date.accessioned | 2018-10-30T05:59:14Z | - |
dc.date.available | 2018-10-30T05:59:14Z | - |
dc.date.created | 2018-10-30 | - |
dc.date.issued | 2018-11 | - |
dc.identifier.citation | Angewandte Chemie - International Edition, v.57, no.45, pp.14852 - 14856 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/9362 | - |
dc.description.abstract | Titanium(IV)-based metal-organic frameworks (Ti-MOFs) have received significant attention in recent years due to their numerous photocatalytic applications. We herein prepare the single-crystalline Ti-carboxylate MOF (DGIST-1) composed of an unprecedented Ti-oxo chain cluster and the porphyrinic ligand, TCPP (tetrakis(4-carboxyphenyl)porphyrin). Preformed Ti-oxo clusters were used as Ti4+ sources to avoid the spontaneous hydrolysis and condensation reactions of traditional Ti-alkoxide precursors, thus, enabling the formation of the highly crystalline Ti-MOF. The successfully activated DGIST-1 exhibited a higher surface area (i.e., 1957.3 m2 g−1) than previously reported Ti-MOFs due to its high crystallinity. Furthermore, the visible-light-responsive photocatalytic activity of DGIST-1 was confirmed by the simultaneous generation of singlet oxygen (1O2) and superoxide (.O2 −) species, in addition to the highly efficient and selective oxidation of benzyl alcohol to benzaldehyde. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.language | English | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | Titanium-Carboxylate Metal-Organic Framework Based on an Unprecedented Ti-Oxo Chain Cluster | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.201809762 | - |
dc.identifier.wosid | 000452234400029 | - |
dc.identifier.scopusid | 2-s2.0-85054740968 | - |
dc.type.local | Article(Overseas) | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.citation.publicationname | Angewandte Chemie - International Edition | - |
dc.contributor.nonIdAuthor | Keum, Yesub | - |
dc.contributor.nonIdAuthor | Park, Seonghun | - |
dc.contributor.nonIdAuthor | Chen, Ying-Pin | - |
dc.identifier.citationVolume | 57 | - |
dc.identifier.citationNumber | 45 | - |
dc.identifier.citationStartPage | 14852 | - |
dc.identifier.citationEndPage | 14856 | - |
dc.identifier.citationTitle | Angewandte Chemie - International Edition | - |
dc.type.journalArticle | Article | - |
dc.description.isOpenAccess | N | - |
dc.subject.keywordAuthor | cluster compounds | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordAuthor | reactive oxygen species | - |
dc.subject.keywordAuthor | selective alcohol oxidation | - |
dc.subject.keywordAuthor | Ti-oxo chain cluster | - |
dc.subject.keywordPlus | SINGLET OXYGEN | - |
dc.subject.keywordPlus | CO2 REDUCTION | - |
dc.subject.keywordPlus | PHOTOCATALYSIS | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | MECHANISMS | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | MOF | - |
dc.contributor.affiliatedAuthor | Keum, Yesub | - |
dc.contributor.affiliatedAuthor | Park, Seonghun | - |
dc.contributor.affiliatedAuthor | Chen, Ying-Pin | - |
dc.contributor.affiliatedAuthor | Park, Jinhee | - |
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